Visible Light [2 + 2] Cycloadditions of Thermoresponsive Dendronized Styryltriazines To Exhibit Tunable Microconfinement DOI
Sijie Zhou, Mengjie Zhang, Yuan Yue

et al.

ACS Macro Letters, Journal Year: 2024, Volume and Issue: 13(7), P. 866 - 873

Published: June 27, 2024

Visible light-triggered photochemical reactions in aqueous media are highly valuable to tailor molecular structures and properties an ecofriendly manner. Here we report visible light-induced catalyst-free [2 + 2] cycloadditions of thermoresponsive dendronized styryltriazines, which show tunable microconfinement guest dyes media. These styryltriazines constituted conjugated mono- or tristyryltriazines, carry hydrophilic dendritic oligoethylene glycol (OEG) pendants. They underwent efficient form cyclobutane dimers oligomers water through irradiation with light 400 nm, their cycloaddition behavior was dominated by architectures solvent conditions. Dendronization OEGs also afforded them characteristic phase transition temperatures the range 36-65 °C, can be further modulated photocycloaddition styryltriazine chromophores. Importantly, microenvironments media, encapsulate hydrophobic solvatochromic Nile red exhibit variable photophysical properties. The encapsulated dye simultaneously released noninvasive reactions.

Language: Английский

In situ visualization of polymer solution phase transition using photoresponsive tracers and Förster resonance energy transfer enabled by MXene quantum dots DOI

Arman Motalebnejad-Mamaqani,

Milad Babazadeh‐Mamaqani, Hossein Roghani‐Mamaqani

et al.

Materials Today Chemistry, Journal Year: 2025, Volume and Issue: 45, P. 102670 - 102670

Published: April 1, 2025

Language: Английский

Citations

0
Visible Light [2 + 2] Cycloadditions of Thermoresponsive Dendronized Styryltriazines To Exhibit Tunable Microconfinement DOI
Sijie Zhou, Mengjie Zhang, Yuan Yue

et al.

ACS Macro Letters, Journal Year: 2024, Volume and Issue: 13(7), P. 866 - 873

Published: June 27, 2024

Visible light-triggered photochemical reactions in aqueous media are highly valuable to tailor molecular structures and properties an ecofriendly manner. Here we report visible light-induced catalyst-free [2 + 2] cycloadditions of thermoresponsive dendronized styryltriazines, which show tunable microconfinement guest dyes media. These styryltriazines constituted conjugated mono- or tristyryltriazines, carry hydrophilic dendritic oligoethylene glycol (OEG) pendants. They underwent efficient form cyclobutane dimers oligomers water through irradiation with light 400 nm, their cycloaddition behavior was dominated by architectures solvent conditions. Dendronization OEGs also afforded them characteristic phase transition temperatures the range 36-65 °C, can be further modulated photocycloaddition styryltriazine chromophores. Importantly, microenvironments media, encapsulate hydrophobic solvatochromic Nile red exhibit variable photophysical properties. The encapsulated dye simultaneously released noninvasive reactions.

Language: Английский

Citations

1