Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(22), P. 10358 - 10365
Published: May 20, 2024
Core–shell
nanocrystals
(C–S
NCs)
are
an
essential
class
of
materials
whose
structural
engineering
has
attracted
wide
attention
due
to
their
tunable
optical
and
electrical
properties,
especially
noble
metal@semiconductor
(NMS)
C–S
NCs
with
flexible
plasmon-exciton
coupling.
Due
diverse
critical
applications,
aqueous
biological
herein
we
propose
topological
strategy
enabled
by
cation
exchange
reactions
(CER)
synthesize
various
plasmonic
Au@semiconductor
NCs,
in
which
environmentally
friendly
triphenylphosphine
(TPP)
is
used
as
initiator
instead
inflammable
tributyl
phosphine
(TBP).
The
introduction
the
milder,
solid
TPP
facilitated
a
new
CER
for
synthesizing
tailored
chalcogenide
compositions
morphologies.
For
example,
as-synthesized
Au@ZnS
NRs
had
better
absorption
biocompatibility
exhibited
excellent
photodynamic
therapy
efficacy.
Nano Letters,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 1, 2024
The
key
to
optimizing
photocatalysts
lies
in
the
efficient
separation
and
oriented
migration
of
photogenerated
carriers.
Herein,
we
report
that
breaking
continuous
TiO
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(22), P. 10358 - 10365
Published: May 20, 2024
Core–shell
nanocrystals
(C–S
NCs)
are
an
essential
class
of
materials
whose
structural
engineering
has
attracted
wide
attention
due
to
their
tunable
optical
and
electrical
properties,
especially
noble
metal@semiconductor
(NMS)
C–S
NCs
with
flexible
plasmon-exciton
coupling.
Due
diverse
critical
applications,
aqueous
biological
herein
we
propose
topological
strategy
enabled
by
cation
exchange
reactions
(CER)
synthesize
various
plasmonic
Au@semiconductor
NCs,
in
which
environmentally
friendly
triphenylphosphine
(TPP)
is
used
as
initiator
instead
inflammable
tributyl
phosphine
(TBP).
The
introduction
the
milder,
solid
TPP
facilitated
a
new
CER
for
synthesizing
tailored
chalcogenide
compositions
morphologies.
For
example,
as-synthesized
Au@ZnS
NRs
had
better
absorption
biocompatibility
exhibited
excellent
photodynamic
therapy
efficacy.