Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: unknown, P. 136084 - 136084
Published: Dec. 1, 2024
Language: Английский
Advanced Science, Journal Year: 2024, Volume and Issue: 11(42)
Published: Sept. 16, 2024
Abstract The rapid advancement in attractive platforms such as biomedicine and human‐machine interaction has generated urgent demands for intelligent materials with high strength, flexibility, self‐healing capabilities. However, existing ability are challenged by a trade‐off between low elastic modulus, healing due to the inherent strength of noncovalent bonding. Here, drawing inspiration from human fibroblasts, monomer trapping synthesis strategy is presented based on dissociation reconfiguration amphiphilic ionic restrictors (7000‐times volume trapping) develop eutectogel. Benefiting nanoconfinement dynamic interfacial interactions, molecular chain backbone formed confined domains mechanically reinforced while preserving soft movement resulting eutectogels demonstrate superior mechanical properties (1799% 2753% higher tensile toughness than pure polymerized deep eutectic solvent), excellent efficiency (>90%), tangential modulus (0.367 MPa during working stage), sensitively monitor activities. This poised offer new perspective developing wearable electronics tailored body motion.
Language: Английский
Citations
16
Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 2, 2025
Abstract Event‐driven sensors are essential for real‐time applications, yet the integration of current technologies faces limitations such as high cost, complex signal processing, and vulnerability to noise. This work introduces a bio‐inspired mechanoluminescence visuotactile sensor that enables standard frame‐based cameras perform event‐driven sensing by emitting light only under mechanical stress, effectively acting an event trigger. Drawing inspiration from biomechanics canine teeth, utilizes rod‐patterned array enhance mechanoluminescent sensitivity expand contact surface area. In addition, machine learning‐enabled algorithm is designed accurately analyze interaction‐triggered in real‐time. The integrated into quadruped robot's mouth interface, demonstrating enhanced interactive capabilities. system successfully classifies eight activities with average accuracy 92.68%. Comprehensive tests validate sensor's efficacy capturing dynamic tactile signals broadening application scope robots interaction environment.
Language: Английский
Citations
2
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Aug. 26, 2024
Abstract Compared to conventional gels, eutectogels encompassing deep eutectic solvents (DESs) circumvent the shortboards including poor temperature resistance, high cost, and undesired toxicity. However, existing suffer weak intra‐ interchain interactions, which culminates in vanishing autofluorescence, mechanic feeble adhesion. Although myriad strategies have been proposed boost polymer/polymer interactions within processes are time‐consuming, not suitable for mass production or emergent deployment. Herein, deal with it, a facile solvation chemistry is leveraged build dynamic rigid network via incorporating active polymer backbones DESs. Within these eutectogels, DESs play magnet‐like role, physically cluster chains together multiple noncovalent forces, thus intensifying DESs/polymer interactions. This bestows rare autofluorescence unprecedentedly strength, toughness, adhesion among reported analogues, even harsh conditions. Moreover, mechanism of fully scrutinized first time. It believed that this strategy can be easily expanded orchestrations other soft materials.
Language: Английский
Citations
5
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 27, 2024
Abstract The powerful capability of multi‐stimulus‐responsive fluorescent hydrogen‐bonded organic frameworks (HOFs) to respond external chemical or physical stimuli in various manners makes them appealing advanced information encryption. However, it is still a global challenge manipulate the fluorescence properties finely achieve dynamic time dimension. Here, feasible strategy shown control emission materials by introducing common SP photochromic compound (1′, 3′, 3′‐trimethyl‐6‐nitro‐spiro‐ [chromene‐2, 2′‐indoline]) into functionalized HOFs, properties. Two kinds HOFs are successfully synthesized modifying unbonded carboxylic group with Tb 3+ 5‐hexene‐1‐ol termed Tb‐HOFs and HOF‐olefin, respectively. Then, spiropyran loaded HOFs‐olefin can be well controlled changing lanthanide dopants light stimulation time. Relying on emission, multilevel encryption including anti‐counterfeiting ink, QR code, base time‐resolved storage has been demonstrated, security level greatly improved. This work opens an avenue for achieving technology, where “time factor” equivalent key, which introduces countless unpredictable possibilities imitation more challenging.
Language: Английский
Citations
5
Nanoscale, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Multifunctional coupling and signal decoupling achieved through nanostructure supramolecule design, enable multimodal mechanoluminescent materials to play an increasingly important role in interdisciplinary applications cutting-edge fields.
Language: Английский
Citations
0
Carbohydrate Polymers, Journal Year: 2025, Volume and Issue: 357, P. 123444 - 123444
Published: Feb. 26, 2025
Language: Английский
Citations
0
Chemistry - An Asian Journal, Journal Year: 2025, Volume and Issue: unknown
Published: April 8, 2025
Abstract Mechanochromic polymers have potential in visualization of microscopic damages materials, and the integration non‐invasive switching into mechanochromic can enable rich on‐demand functionality polymer materials. In this work, we report development a mechanoresponsive fluorescent with photogated properties, comprising poly(methyl acrylate) (PMA) photoswitchable mechanophore S 2 A , which features two anthracene groups linked by disilane spacer. The PMA‐S exhibits ratiometric fluorescence response upon mechanical deformation, arises from monomer excimer emission ratio controlled strain. property be switched off irradiation 365 nm UV light induces [4 + 4] cycloaddition between within chains. Importantly, dimers reversibly dissociated situ film 254 UV, restoring function. Furthermore, intermolecular photodimerization increases molecular weight forms an entanglement network, significantly enhancing material toughness. This reversible photocontrolled switch design offers novel strategy for developing materials modulated responses properties.
Language: Английский
Citations
0
Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: unknown, P. 136084 - 136084
Published: Dec. 1, 2024
Language: Английский
Citations
0