Electron effect regulation: A study on the influence of electron-donating and withdrawing group modification on the performance of metal-coordinated catalysts for electrochemical carbon dioxide reduction DOI

Jiaqi Yu,

Hongsen Zhang,

Qi Liu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 683, P. 387 - 397

Published: Dec. 14, 2024

Language: Английский

Modulating *CO adsorption configuration over the CuPd/Cu interfaces to improve C-C coupling for enhanced acetate production DOI
Wei Wei,

Zhenyao Li,

Jitao Shang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: 371, P. 125220 - 125220

Published: March 3, 2025

Language: Английский

Citations

0

CuMoRuFeW high entropy alloy surfaced nanorods: superior electrochemical CO2 reduction to ethylene DOI

Jundi Qin,

Dan Hu,

Dong Xiang

et al.

Chinese Journal of Structural Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 100571 - 100571

Published: March 1, 2025

Language: Английский

Citations

0

Turning the Selectivity of CO Electroreduction from Acetate to Ethanol by Alloying FCC-Phased Cu with Atomically Dispersed Mn Atoms DOI
Zhipeng Chen, Yusi Zhao, Gen Liu

et al.

Nano Letters, Journal Year: 2025, Volume and Issue: unknown

Published: April 10, 2025

The predominant product of CO electroreduction (COER) is often acetate, with the Faradaic efficiency (FE) for ethanol usually falling below 50%. Herein, we propose a unique strategy to enhance selectivity in COER, shifting it from acetate predominance toward generation via alloying atomic manganese (Mn) atoms face-centered cubic (FCC) copper (Cu) catalyst. By optimizing ratio Mn Cu, observe an impressive enhancement 8.8-fold ethanol-to-acetate FE optimal Mn3Cu97 alloy compared unalloyed FCC-phase Cu. demonstrates remarkable nearly 70% at high current density 600 mA cm-2 membrane electrode assembly electrolyzer. Further theoretical analysis reveals that atomically dispersed generate synergistic active sites and modulate adsorption strength critical intermediates relevant synthesis, thereby facilitating transition pathway pathway.

Language: Английский

Citations

0

Dynamic active sites behind Cu-based electrocatalysts: Original or restructuring-induced catalytic activity DOI Creative Commons
Shuai Chen,

Farzaneh Farzinpour,

Nikolay Kornienko

et al.

Chem, Journal Year: 2025, Volume and Issue: unknown, P. 102575 - 102575

Published: May 1, 2025

Language: Английский

Citations

0

Multi-atomic catalysts: Pioneering applications in the pursuit of carbon neutrality DOI
Jiarui Yang, Dingsheng Wang

Carbon Future, Journal Year: 2024, Volume and Issue: 1(3), P. 9200019 - 9200019

Published: Sept. 1, 2024

Language: Английский

Citations

2

Electron effect regulation: A study on the influence of electron-donating and withdrawing group modification on the performance of metal-coordinated catalysts for electrochemical carbon dioxide reduction DOI

Jiaqi Yu,

Hongsen Zhang,

Qi Liu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 683, P. 387 - 397

Published: Dec. 14, 2024

Language: Английский

Citations

2