Silver(i) Perfluoroalcoholates: Synthesis, Structure, and their Use as Transfer Reagents

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: 30(33)

Published: April 12, 2024

Herein we report a general access to silver(i) perfluoroalcoholates, their structure in the solid state and solution, use as transfer reagents. The perfluoroalcoholates are prepared by reaction of AgF with corresponding perfluorinated carbonyl compounds acetonitrile stable for prolonged time at -18 °C. X-ray analysis single crystals perfluoroalcoholate species showed that two Ag(i) centers bridged alcoholate ligands. In Ag[OCF

Language: Английский

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Copper(I) Iodide-Catalyzed Perfluoroalkoxylation Reaction of Alkyl Halides

Organic Letters, Journal Year: 2024, Volume and Issue: 26(34), P. 7139 - 7143

Published: Aug. 15, 2024

We report an efficient perfluoroalkoxylation reaction of alkyl halides catalyzed by copper(I) iodide (CuI), which facilitates the simultaneous activation both perfluoroalkoxide and halides. This methodology is tolerant a wide range functional groups eliminates need for costly metal reagents. The conducted in single step under mildly practical conditions.

Language: Английский

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Recent advances in silver-mediated/catalyzed synthesis of trifluoromethoxy compounds

Science China Chemistry, Journal Year: 2024, Volume and Issue: 68(5), P. 1717 - 1730

Published: Nov. 4, 2024

Language: Английский

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Recent Progress on Methods for the Preparation of Mono/Di/Trifluoromethoxylation Reagents

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(11), P. 3321 - 3321

Published: Jan. 1, 2024

Language: Английский

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