Synthesis,
Journal Year:
2021,
Volume and Issue:
54(03), P. 517 - 534
Published: Sept. 29, 2021
Abstract
Recent
developments
in
manganese-catalyzed
reducing
transformations—hydrosilylation,
hydroboration,
hydrogenation,
and
transfer
hydrogenation—are
reviewed
herein.
Over
the
past
half
a
decade
(i.e.,
2016
to
present),
more
than
115
research
publications
have
been
reported
these
fields.
Novel
organometallic
compounds
new
reduction
transformations
discovered
further
developed.
Significant
challenges
that
had
historically
acted
as
barriers
for
use
of
manganese
catalysts
reactions
are
slowly
being
broken
down.
This
review
will
hopefully
assist
developing
this
area,
by
presenting
clear
concise
overview
catalyst
structures
substrate
published
so
far.
1
Introduction
2
Hydrosilylation
3
Hydroboration
4
Hydrogenation
5
Transfer
6
Conclusion
Perspective
ACS Omega,
Journal Year:
2022,
Volume and Issue:
7(42), P. 37008 - 37038
Published: Oct. 11, 2022
In
recent
years,
many
manganese-based
homogeneous
catalytic
precursors
have
been
developed
as
powerful
alternatives
in
organic
synthesis.
Among
these,
the
hydrofunctionalizations
of
unsaturated
C–C
bonds
correspond
to
outstanding
ways
afford
compounds
with
more
versatile
functional
groups,
which
are
commonly
used
building
blocks
production
fine
chemicals
and
feedstock
for
industrial
field.
Herein,
we
present
an
account
Mn-catalyzed
alkenes
alkynes
main
objective
finding
mechanistic
tendencies
that
could
serve
a
platform
works
come.
ChemCatChem,
Journal Year:
2023,
Volume and Issue:
15(15)
Published: April 19, 2023
Abstract
In
the
last
two
decades,
pincer
metal
complexes
have
been
highly
utilized
as
catalysts
for
a
variety
of
organic
transformations
in
both
industrial
and
social
applications.
Owing
to
extraordinary
chemical
characteristics,
such
extra
thermal
stability
easy
functionalization,
they
were
extensively
generating
novel
catalytic
species.
Besides,
activity
these
was
achieved
with
high
atom
economy
eco‐friendly
routes.
Recently,
exhibited
excellent
behaviour
towards
various
immerging
systems,
hydrogenation
CO
2
,
nitriles,
amides,
esters,
olefins
alkynes,
which
are
valuable
production,
academic
research,
green
environment.
The
main
goal
this
reviewwas
highlight
how
function
reactions,
well
their
mechanistic
studies.
Specifically,
we
focus
on
most
updated
advancements
few
years.
Some
outlooks
future
suggestions
further
related
work
conclude
paper.
