Halogen bond promoted aryl migration of allylic alcohols under visible light irradiation DOI

Keyuan Zhang,

Yulong Wang,

Chonglong He

et al.

Organic Chemistry Frontiers, Journal Year: 2022, Volume and Issue: 9(20), P. 5599 - 5605

Published: Jan. 1, 2022

A simple and catalyst-free radical addition/1,2-aryl migration cascade process of ally alcohol driven by halogen bond was developed under visible light irradiation, featuring mild conditions, practical procedures, broad substrate scope.

Language: Английский

Visible light-induced perfluoroalkylation reaction of indoles in the presence of Na2-eosin Y DOI
Xiaoxiao He, Du Chen, Zhenjiang Liu

et al.

Tetrahedron Letters, Journal Year: 2025, Volume and Issue: 162, P. 155571 - 155571

Published: April 11, 2025

Language: Английский

Citations

0
Visible light-induced phosphine-catalyzed perfluoroalkylation of indoles DOI

Xiuhui Gao,

Xuling Pan,

Peiyi Wang

et al.

Organic Chemistry Frontiers, Journal Year: 2022, Volume and Issue: 9(21), P. 5790 - 5797

Published: Jan. 1, 2022

A photo-induced, catalytic PPh 3 -promoted perfluoroalkylation reaction of indole molecules is developed to give perfluoroalkylated products in moderate excellent yields, which 13 F-containing indoles exhibited good antibacterial activities.

Language: Английский

Citations

15
Frustrated-radical-pair-initiated atom transfer radical addition of perfluoroalkyl halides to alkenes DOI

Fuyu Xie,

Jianghua He, Yuetao Zhang

et al.

Organic Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 10(15), P. 3861 - 3869

Published: Jan. 1, 2023

We employed a frustrated radical pair to catalyze the atom-transfer addition of perfluoroalkyl halides alkenes, which furnished series fluoroalkylated compounds in high regioselectivity and high-to-excellent product yields.

Language: Английский

Citations

9
Visible-Light Photoredox Catalysis for the Synthesis of Fluorinated Aromatic Compounds DOI Open Access
Tomasz Kliś

Catalysts, Journal Year: 2023, Volume and Issue: 13(1), P. 94 - 94

Published: Jan. 2, 2023

Fluorine-containing functional groups are important motifs influencing physical and biological properties of organic compounds. Visible-light photoredox catalysis as a powerful strategy for the activation small molecules contributed significantly to rapid progress new synthetic procedures allowing introduction fluorine atoms into substrates. In this review, we highlight distinct strategies transition metal- organic-photocatalytic fluorination arenes heteroarenes by broad range fluorinating The presented divided two groups. first group involves reactions enabling direct attachment CF3-, CnFm-, F-, CF3O-, CF3S-, SO2F- substituents various aromatic second presents tandem where formation system occurs after installation fluorine-containing on non-aromatic fragment molecule.

Language: Английский

Citations

8
Halogen bond promoted aryl migration of allylic alcohols under visible light irradiation DOI

Keyuan Zhang,

Yulong Wang,

Chonglong He

et al.

Organic Chemistry Frontiers, Journal Year: 2022, Volume and Issue: 9(20), P. 5599 - 5605

Published: Jan. 1, 2022

A simple and catalyst-free radical addition/1,2-aryl migration cascade process of ally alcohol driven by halogen bond was developed under visible light irradiation, featuring mild conditions, practical procedures, broad substrate scope.

Language: Английский

Citations

12