Journal of Organic Chemistry Research, Journal Year: 2023, Volume and Issue: 11(04), P. 268 - 284
Published: Jan. 1, 2023
Language: Английский
Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(8)
Published: Jan. 8, 2024
A mild photoredox catalyzed construction of sulfides, disulfides, selenides, sulfoxides and sulfones from unstrained ketone precursors is introduced. Combination this deacylative process with S
Language: Английский
Citations
21
European Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 27(23)
Published: May 25, 2024
Abstract Sulfonyl fluorides have widespread applications in many fields, including organic synthesis, chemical biology, drug discovery and materials science. In particular, the past decade, a number of aliphatic sulfonyl been identified showing various biological activities. These appealing features brought about significant advancement developing synthetic methods to access fluorides. this review, we will discuss recent developments radical approaches for synthesis
Language: Английский
Citations
12
Organic Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 11(1), P. 217 - 235
Published: Nov. 14, 2023
This review summarizes the latest achievements in photochemical and electrochemical strategies for synthesis of sulfonyl fluorides focuses on novel features proposed mechanisms.
Language: Английский
Citations
22
European Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 27(9)
Published: Feb. 8, 2024
Abstract Cycloalkanols ring‐opening transformation is one of the most valuable and wide area research. Among numerous methods that have been developed, transition‐metal‐free approaches attracted great interest from both chemists pharmacologists. This largely due to advantages being environmentally benign, cost‐effective operationally simple. Here we provide a comprehensive outline on recent advances in synthesis distally substituted ketones cyclic compounds via cycloalkanols under conditions.
Language: Английский
Citations
6
Green Chemistry, Journal Year: 2024, Volume and Issue: 26(3), P. 1375 - 1380
Published: Jan. 1, 2024
A visible-light-mediated tandem ring opening/1,6-conjugate addition of cyclobutanols with p -quinone methides was developed. This protocol allowed the formation δ,δ-diaryl ketones in presence a readily available organic photocatalyst.
Language: Английский
Citations
5
Organic Letters, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 27, 2025
A palladium-catalyzed alkoxycarbonylation with two different alcohols for the synthesis of cyclobutanecarboxylates bearing an α-quaternary carbon center is presented. The reaction utilizes readily accessible starting materials, tolerates a broad scope functional groups, and provides straightforward efficient approach diverse array carbon. Meanwhile, this strategy effectively prevents transition-metal-catalyzed ring-opening cyclobutanols, preserves cyclobutane framework, affords 1,1-disubstituted in high yields excellent regioisomeric ratios.
Language: Английский
Citations
0
Organic Letters, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 6, 2025
This study reported a novel and unprecedented photoredox-catalyzed protocol for direct allylic C–H fluorosulfonylation of alkenes with FABI. mild exhibited excellent compatibility various functional groups, broad substrate scope, promising scalability, enabling convenient access to wide range allyl sulfonyl fluorides exceptional regioselectivity. The synthetic robustness this strategy was further demonstrated by the late-stage functionalization natural products their ligation other drugs via SuFEx chemistry.
Language: Английский
Citations
0
The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: March 16, 2025
A photocatalytic radical sulfonarylation of N-arylacrylamides via a three-component cascade cyclopropyl alcohol ring opening/sulfur dioxide insertion/sulfonyl addition/cyclization sequence has been developed. This method employs alcohols as the precursors β-carbonyl alkyl radicals and Na2S2O5 cheap source sulfur dioxide. By using this procedure, wide variety γ-keto-sulfone-substituted oxindoles were facilely synthesized.
Language: Английский
Citations
0
Chemical Reviews, Journal Year: 2025, Volume and Issue: unknown
Published: April 22, 2025
Fluorine and nitrogen form a successful partnership in organic synthesis, medicinal chemistry, material sciences. Although fluorine-nitrogen chemistry has long rich history, this field received increasing interest made remarkable progress over the past two decades, driven by recent advancements transition metal organocatalysis photochemistry. This review, emphasizing contributions from 2015 to 2023, aims update state of art synthesis applications nitrogen-based organofluorine functional molecules chemistry. In dedicated sections, we first focus on fluorine-containing reagents organized according type groups attached nitrogen, including N-F, N-RF, N-SRF, N-ORF. review also covers nitrogen-linked building blocks, catalysts, pharmaceuticals, agrochemicals, underlining these components' broad applicability growing importance modern
Language: Английский
Citations
0
Journal of Fluorine Chemistry, Journal Year: 2025, Volume and Issue: 283-284, P. 110425 - 110425
Published: April 1, 2025
Language: Английский
Citations
0