Photoinduced Single Electron Transfer via EDA Complexation Enables Decarbonylative C(sp2)–S Bond Formation DOI
Swagata Choudhury, Sudipta Raha Roy

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 18, 2024

We have developed a photoinduced transition-metal-free decarbonylative strategy at ambient temperature through non-covalent interactions to achieve vinyl sulfones. Traditionally, functionalization is accomplished using transition metal catalysts elevated temperatures. The π–π interaction facilitates the elimination of CO generate radical, thereby promoting creation C–S bonds with sulfonyl radical. These and overall process were illuminated by spectroscopic investigations mechanistic studies.

Language: Английский

Highly efficient photoelectrochemical azido-hydroxylation of alkenes by metal-free tandem addition of two radicals DOI
Jie Yang, Yu Lei, Youji Li

et al.

Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 19, 2025

Language: Английский

Citations

0
Biaryl Ligation Promoted by Catalyst-based π–π Stacking DOI
Dahui Zhao, Jianjun Han

Synfacts, Journal Year: 2024, Volume and Issue: 20(05), P. 0470 - 0470

Published: April 15, 2024

Key words biaryl syntheses - π–π stacking aryl acetylene photocatalysis

Language: Английский

Citations

0
Photoinduced Single Electron Transfer via EDA Complexation Enables Decarbonylative C(sp2)–S Bond Formation DOI
Swagata Choudhury, Sudipta Raha Roy

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 18, 2024

We have developed a photoinduced transition-metal-free decarbonylative strategy at ambient temperature through non-covalent interactions to achieve vinyl sulfones. Traditionally, functionalization is accomplished using transition metal catalysts elevated temperatures. The π–π interaction facilitates the elimination of CO generate radical, thereby promoting creation C–S bonds with sulfonyl radical. These and overall process were illuminated by spectroscopic investigations mechanistic studies.

Language: Английский

Citations

0