Cited by Decarboxylative Cross-Coupling of Aryl Carboxylic Acids with Arylboronic Acids Using Ag/ZnO Catalyst under Aerobic Conditions in Aqueous Medium

Transition-metal-, oxidant- and additive-free multi-component synthesis of alkyl heteroaryl BCPs enabled by visible-light-induced phosphine-catalyzed halogen-atom transfer DOI

Jun Xu,

Yu Hong,

Ruiyuan Xu

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This study describes a pioneering visible-light-induced phosphine-catalyzed halogen-atom transfer (XAT) strategy that heralds new era in the difunctionalization of [1.1.1]propellane.

Language: Английский

Citations

Advances and perspectives on photochemical/electrochemical synthesis of nitrogen, sulfur, and phosphorus heteroatom containing compounds from biomass-based feedstocks DOI

Hanjing Tian,

Anping Wang, Pan Hu

et al.

Industrial Crops and Products, Journal Year: 2024, Volume and Issue: 222, P. 119738 - 119738

Published: Sept. 27, 2024

Language: Английский

Citations

Decatungstate-Photocatalyzed Hydroamidomethylation of Azobenzenes with N,N-Dimethylamides DOI

Jingya Yang,

Cunhui Wang,

Yating Han

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 19, 2024

A photocatalytic hydroamidomethylation of azobenzenes with N,N-dimethylamides has been developed. Using tetrabutylammonium decatungstate (TBADT) as a photocatalyst, an array and reacted smoothly under visible light irradiation, affording previously unreported N-amidomethyl-N,N′-diarylhydrazines in generally high yields. Mechanistic studies indicate that the reaction is enabled by TBADT-mediated hydrogen atom transfer (HAT) photocatalysis. This work fundamentally different from reported N,N-dimethylformamide azobenzenes.

Language: Английский

Citations

Catalyst‐free visible light‐induced N‐N bond cleavage for the synthesis of iminophosphorane using triarylphosphine and N‐sulfonyl and N‐acylaminopyridinium salt DOI

Xiaotao Qin,

Chenglei Yang,

Yinjiang Xue

et al.

European Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 1, 2025

Abstract Herein, we explore a visible light‐enabled radical addition for the construction of N‐sulfonyl and N‐acyliminophosphorane using triarylphosphine N‐acylaminopyridinium salts in absence transition metal, photocatalyst, oxidant or base. This method employs PAr 3 as both reaction catalyst to promote generation amidyl via N−N bond cleavage salts, materials preparation products. transformation exhibits abroad substrate scope good functional group compatibility.

Language: Английский

Citations

Electrochemical Strategy for the Radical Fluoroacetylation of Sulfoximines from Fluorinated Alkyl Carboxylic Acids DOI

Xiaoman Li, Jiawei Huang, Huanhuan Song

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: April 15, 2025

The integration of trifluoroacetyl (CF3CO) groups into organic skeletons is a key research topic in synthetic chemistry given their significant potential to boost biological activity. Despite recent developments strategies for incorporating moiety via radical intermediates, the practical utilization inexpensive and readily available trifluoroacetic acids as sources has not yet been developed. Herein, an electrochemical strategy employed achieve deoxygenative transformation directly with assistance PPh3. obtained radicals are then coupled sulfoximine species, thus enabling synthesis N-trifluoroacetylated sulfoximines. Additionally, other fluorinated alkyl carboxylic acids, including perfluoro-, difluoro-, trifluoromethylcarboxylic can also be efficiently utilized under these conditions, leading corresponding acylated Moreover, trifluoroacetylation drug-based molecules easy execution scale-up experiments highlight applicability this protocol.

Language: Английский

Citations

Photoredox-Catalyzed Radical Hydroalkylation of Azobenzenes with Alkylboronic Acids DOI

Jiangjiang Li,

Hongyan Zhou,

Shouying Mei

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: April 18, 2025

The facile synthesis of N-alkyl-N,N'-diarylhydrazines has been a long-standing challenge. Here, we report photoredox-catalyzed hydroalkylation azobenzenes with alkylboronic acids, which successfully affords diverse N-alkyl-N,N'-diarylhydrazines. With an acridinium salt as the photocatalyst and upon visible light irradiation, broad range acids reacted smoothly in presence Lewis base at ambient temperature. Mechanistic studies revealed that reaction proceeds via generation alkyl radicals is facilitated by photoredox catalysis.

Language: Английский

Citations

Visible-Light-Promoted Oxidative Decarboxylative Acylation of Acenaphthenone-2-ylidene ketones with α-Keto Carboxylic Acids under Metal , Additonal Oxidant and Base-free condition DOI

Tiyasa Dhar,

Debasish Bera, Suvendu Maity

et al.

Tetrahedron, Journal Year: 2025, Volume and Issue: unknown, P. 134674 - 134674

Published: April 1, 2025

Language: Английский

Citations

Generation of alkyl and acyl radicals by visible-light photoredox catalysis: direct activation of C–O bonds in organic transformations DOI

Mithu Roy,

Bitan Sardar,

Itu Mallick

et al.

Beilstein Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 20, P. 1348 - 1375

Published: June 14, 2024

Alkyl and acyl radicals play a critical role in the advancement of chemical synthesis. The generation alkyl by activation C – O bonds using visible-light photoredox catalysis offers mild environmentally benign approach to useful transformations. Alcohols, carboxylic acids, anhydrides, xanthates, oxalates, N -phthalimides, thiocarbonates are some examples precursors that can produce reactive homolysis bond. These then go through variety transformations beneficial for construction synthetic materials otherwise difficult access. This study summarizes current developments use organic photocatalysts, transition-metal catalysts, metallaphotocatalysts driven visible light.

Language: Английский

Citations

Visible-light-induced copper-catalyzed regiodivergent C(sp³)-sulfonylation of oxime esters with sodium sulfinates DOI

Ben Ma, Zhiyong Chen, Min Ma

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(20), P. 5876 - 5883

Published: Jan. 1, 2024

A visible-light-induced copper-catalyzed regiodivergent sulfonylation of oxime esters with sodium sulfinates under mild conditions is reported, yielding a range useful β-ketosulfones and sulfonated pyrrolines convertible functional groups.

Language: Английский

Citations

Shaping cycles with light: a regiodivergent approach to tetracyclic aza-aromatic compounds DOI

Clara Mañas,

Belén Ibarra,

Estı́baliz Merino

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

We present a novel visible light-promoted regiodivergent cyclization, enabling the selective synthesis of distinct azapolyaromatic regioisomers from 2-alkynlazobenzenes.

Language: Английский

Citations