Energy‐transfer Enabled Divergent Synthesis of Polycyclic γ‐Sultines DOI
Pan Zhou, Yongxin Zhang, Xinyue Ma

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: July 14, 2024

A visible-light-initiated energy-transfer enabled radical cyclization for the divergent synthesis of polycyclic γ-sultine derivatives has been developed. The reaction provides an alternative and expeditious access to benzofused frameworks, analogues γ-lactones γ-sultones, features good functional group compatibility, mild conditions excellent diastereoselectivity. robustness application potential this method have also successfully displayed by two gram-scale reactions sultones. Mechanistic studies indicated transformations through a possible intramolecular homolytic substitution or hydrogen atom transfer process mainly.

Language: Английский

Recent advances in the synthesis and transformations of sulfinate esters DOI Creative Commons
Suguru Yoshida

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Recent sulfinate esters chemistry is summarized in this feature article. Efficient methods to synthesize diverse from readily available starting materials and various modern transformations of are introduced.

Language: Английский

Citations

1
Energy‐transfer Enabled Divergent Synthesis of Polycyclic γ‐Sultines DOI
Pan Zhou, Yongxin Zhang, Xinyue Ma

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: July 14, 2024

A visible-light-initiated energy-transfer enabled radical cyclization for the divergent synthesis of polycyclic γ-sultine derivatives has been developed. The reaction provides an alternative and expeditious access to benzofused frameworks, analogues γ-lactones γ-sultones, features good functional group compatibility, mild conditions excellent diastereoselectivity. robustness application potential this method have also successfully displayed by two gram-scale reactions sultones. Mechanistic studies indicated transformations through a possible intramolecular homolytic substitution or hydrogen atom transfer process mainly.

Language: Английский

Citations

1