1,2-Acylphosphinylation of Styrenes to Access β-Aryl-γ-ketophosphine Oxides by Irradiation-Induced Radical Relay

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 11, 2025

An acylphosphinylation reaction has been devised for the synthesis of β-aryl-γ-ketophosphine oxides, employing styrenes and acyl azolium salts through an irradiation-induced radical relay mechanism. This method effectively constructs C–C C–P bonds while demonstrating excellent functional group tolerance. Mechanistic studies revealed that a radical-addition–coupling–elimination cascade process was involved in this reaction.

Language: Английский

---

Organocatalytic radical aminoacylation of alkenes for β-aminoketone synthesis

Science China Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 14, 2024

Language: Английский

---

Photocatalytic C(sp³)–P and C(sp²)–P Bond Formation via a Phosphorus Radical Cation

Organic Letters, Journal Year: 2024, Volume and Issue: 26(42), P. 9056 - 9061

Published: Oct. 14, 2024

A straightforward method for the phosphorylation of electron-deficient alkenes and aryl alkynes has been developed, leading to C(sp

Language: Английский

---

Copper Mediated sp³-C—N Bond Cleavage for Synthesizing (Diarylmethyl)diarylphosphine Oxides

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(12), P. 3713 - 3713

Published: Jan. 1, 2024

Language: Английский

---