Synthesis of rigidified cyclohexanes enabled by visible-light-induced trifluoroacetylsilane-mediated [2+2] cycloaddition of cyclopropenes DOI

Meixin Wang,

Yizhi Zhang, Shanshan Liu

et al.

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 110758 - 110758

Published: Dec. 1, 2024

Language: Английский

Radical Brook rearrangement: past, present, and future DOI
Yunxiao Zhang, Gang Zhou, Shanshan Liu

et al.

Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

This review aims to provide an overview of radical Brook rearrangement, which is organized by grouping three type reactive species generated via the unique rearrangement process.

Language: Английский

Citations

1
Visible-light-induced organocatalyzed C(sp2)-H bond functionalization of 1,3-azoles with trifluoroacetylsilanes DOI
Zhengyu Li,

Zeguo Zhang,

Zhihan Zhang

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: 67(11), P. 3662 - 3668

Published: Sept. 18, 2024

Language: Английский

Citations

3
Umpolung Synthesis of Selenoesters and Telluroesters via the Photoinduced Coupling of Acylsilanes with Electrophilic Chalcogen Reagents DOI
Ryosuke Masuda,

Yuki Anami,

Hiroyuki Kusama

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 12, 2024

A novel synthesis of selenoesters and telluroesters based on the reactions nucleophilic siloxycarbenes, which were generated by visible-light-induced isomerization corresponding aroyl-, heteroaroyl-, or alkenoylsilanes, with electrophilic chalcogen reagents was developed. The use appropriate selenides ditellurides/Lewis acids enabled coupling at temperatures below ambient temperature a broad substrate scope high functional-group tolerance. To best our knowledge, this is first example synthetic method for involving combination an acylanion equivalent cationic synthons.

Language: Английский

Citations

2
Benzocyclobutenone Synthesis Exploiting Acylsilanes as Photofunctional Directing Groups DOI Creative Commons
Rowan L. Pilkington,

Hannah J. Ross,

Liselle Atkin

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

The visible-light irradiation of acylsilane tethered vinyl ketones promotes an intramolecular Stetter-type reaction

Language: Английский

Citations

1
Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers DOI

Akihisa Matsuura,

Yuri Ito,

Tetsuya Inagaki

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 18216 - 18222

Published: Nov. 25, 2024

A catalytic protocol has been developed to access Fischer carbene nickel complexes using acylsilanes as stable and readily available precursors. The as-generated exhibit versatile reactivity, including cyclopropanation with alkenes, α-C–H insertion reactions, two-component C–H addition norbornene, which demonstrates the broad utility of nickel(0)/acylsilane system for applications complexes.

Language: Английский

Citations

1
Synthesis of rigidified cyclohexanes enabled by visible-light-induced trifluoroacetylsilane-mediated [2+2] cycloaddition of cyclopropenes DOI

Meixin Wang,

Yizhi Zhang, Shanshan Liu

et al.

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 110758 - 110758

Published: Dec. 1, 2024

Language: Английский

Citations

0