Visible-light induced Mallory reaction of tertiary benzanilides via iminium intermediates DOI Creative Commons

Xiaoqiang Ma,

Si Wang,

Zhanyong Tang

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

The Mallory reaction, which involves the photocyclization of stilbenes/diarylethenes and their analogues into polycyclic aromatics, is significant synthetic importance. However, its application to tertiary benzanilides has not been explored date. Besides, most reported reactions require ultraviolet irradiation. In this study, we show first reaction promoted by visible light

Language: Английский

Photoreactions of Semi-Stiff-Diarylethenes Based on the Cyclohexenol Motif DOI

Ekaterina S. Sergeeva,

Anastasia A. Svistova,

Igor Ushakov

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(37), P. 7841 - 7846

Published: Sept. 5, 2024

Nonsymmetric diarylethenes with an additional "stiff" cyclohexenol ring undergo various types of tandem transformations launched by light-induced 6π-photocyclization. Among these, there are two novel reactions (formal [1,3]-H migration and complete aromatization to anthracene derivative) as well photorearrangement formal methane elimination. This diverse reactivity demonstrates the great potential

Language: Английский

Citations

3
Visible-light induced Mallory reaction of tertiary benzanilides via iminium intermediates DOI Creative Commons

Xiaoqiang Ma,

Si Wang,

Zhanyong Tang

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

The Mallory reaction, which involves the photocyclization of stilbenes/diarylethenes and their analogues into polycyclic aromatics, is significant synthetic importance. However, its application to tertiary benzanilides has not been explored date. Besides, most reported reactions require ultraviolet irradiation. In this study, we show first reaction promoted by visible light

Language: Английский

Citations

0