Li3–2xNbxCr2–x(PO4)3 Complex Phosphates with the NASICON Structure: Synthesis and Ionic Conductivity DOI
С. А. Новикова,

A. B. Yaroslavtsev

Membranes and Membrane Technologies, Journal Year: 2024, Volume and Issue: 6(6), P. 433 - 438

Published: Dec. 1, 2024

Language: Английский

Interfacial optimization of Li1.3Al0.3Ti1.7(PO4)3 based solid-state electrolyte by in-situ thermal polymerization for high reliability lithium metal batteries DOI
Tingting Chen, Yuhang Zhang, Yiwei Fan

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162723 - 162723

Published: Feb. 1, 2025

Language: Английский

Citations

0
Design and study of semi-solid-state lithium-ion battery based on LATP electrolyte DOI
Wu Jun, Liurong Shi, Jin Li

et al.

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 120, P. 116487 - 116487

Published: April 7, 2025

Language: Английский

Citations

0
The wide range of battery systems: From micro- to structural batteries, from biodegradable to high performance batteries DOI Creative Commons
Carlos M. Costa, Manuel Salado, Chiara Ferrara

et al.

Progress in Materials Science, Journal Year: 2025, Volume and Issue: unknown, P. 101506 - 101506

Published: May 1, 2025

Language: Английский

Citations

0
Solid-state electrolytes: a way to increase the power of lithium-ion batteries DOI
Daria Voropaeva, И. А. Стенина, A. B. Yaroslavtsev

et al.

Russian Chemical Reviews, Journal Year: 2024, Volume and Issue: 93(6), P. RCR5126 - RCR5126

Published: June 1, 2024

Currently, all-solid-state lithium metal batteries are considered among the most promising energy storage devices, due to their safety and high density. Solid-state electrolytes, key components of batteries, attracting increasing attention. This review presents an analysis important recent advances in field conducting solid-state including mechanisms conductivity, main approaches increase optimization interfaces ways improve stability for types <i>i.e.</i>, inorganic, polymer composite materials. For solid inorganic conductivity have been achieved; however, problems related formation dense thin films a reliable contact with electrode materials still unsolved. Polymer electrolytes characterized by lower which is improved upon plasticization aprotic solvents. Composite it possible achieve combination good mechanical properties along stability, as promising. The solve them outlined.<Br>The bibliography includes 661 references.<Br> Key words: battery, electrolyte, ionic transference numbers

Language: Английский

Citations

3
Research Progress on Solid-State Electrolytes in Solid-State Lithium Batteries: Classification, Ionic Conductive Mechanism, Interfacial Challenges DOI Creative Commons

Shun Ai,

Xianli Wu, Jintao Wang

et al.

Nanomaterials, Journal Year: 2024, Volume and Issue: 14(22), P. 1773 - 1773

Published: Nov. 5, 2024

Solid-state lithium batteries exhibit high-energy density and exceptional safety performance, thereby enabling an extended driving range for electric vehicles in the future. electrolytes (SSEs) are key materials solid-state that guarantee performance of battery. This review assesses research progress on electrolytes, including polymers, inorganic compounds (oxides, sulfides, halides), organic-inorganic composites, challenges related to terms their interfaces, status industrialization electrolytes. For each kind details preparation, properties, composition, ionic conductivity, migration mechanism, structure-activity relationship, collected. faced by batteries, high interfacial resistance, side reactions between electrodes, interface instability, mainly discussed. The current various solid is analyzed regard relevant enterprises from different countries. Finally, potential development directions prospects provides a comprehensive reference SSE researchers paves way innovative advancements batteries.

Language: Английский

Citations

3
Charge Carrier Dynamics of the Mixed Conducting Interphase in All‐Solid‐State Batteries: Lithiated Li1.3Al0.3Ti1.7(PO4)3 as a Case Study DOI Creative Commons
Thomas Scheiber, Bernhard Gadermaier, Matjaž Finšgar

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: June 3, 2024

Abstract All‐solid‐state batteries relying on Li metal as negative electrode material and a ceramic electrolyte may severely suffer from unwanted interfacial processes. Here, 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 (LATP) serve model which is known to form an ionic‐electronic, that is, mixed conducting interphase (MCI) when in contact with metallic or any other source. 1.3+ x = 0.2, 0.6 prepared via ex situ chemical lithiation mimic the formation of MCIs taking place otherwise operando . The preparation large amounts lithiated LATP controlled contents allowed us use nuclear electric techniques study local structures ionic/electronic dynamics detail. results point core‐shell two‐phase morphology Li‐rich phase covering nonlithiated Li‐poor regions. originally poor electronic conductivity σ eon 6.5 × 10 −12 S cm −1 (293 K) increases by ≈3 orders magnitude, hence reaching order 6.6 −9 for 0.6. At even higher loadings ( 1.3), decrease seen, i.e., not exceeding alarming values Quantifying ionic transport processes will help assessing extent damage through MCI discussing whether strategies mitigate such necessary at all.

Language: Английский

Citations

1
Cold-sintering assisted process enables densified and robust fine-grained Li1.3Al0.3Ti1.7(PO4)3 electrolytes for solid-state batteries DOI

Pengpeng Dai,

Yudong Liu, Shanshan Yi

et al.

Journal of Power Sources, Journal Year: 2024, Volume and Issue: 618, P. 235169 - 235169

Published: Aug. 10, 2024

Language: Английский

Citations

1
NASICON-type medium entropy Li1.5Sn1.0Al0.5Zr0.5(PO4)3 electrolyte for solid state Li metal batteries DOI

Pratiksha Gami,

Manish Badole,

Hari Narayanan Vasavan

et al.

Journal of Power Sources, Journal Year: 2024, Volume and Issue: 618, P. 235214 - 235214

Published: Aug. 15, 2024

Citations

1
NASICON Li1.3Al0.3Ti1.7(PO4)3 electrolyte coating enables stable cycling of Li-rich manganese-based cathode DOI
Wei Hu, Xiaoyan Li, Jingqi Huang

et al.

Tungsten, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 24, 2024

Language: Английский

Citations

1
Structural, thermal and electrical properties of Na1+xAlxTi2-xP3O12 (x = 0.3) solid electrolytes DOI Creative Commons
Ademola J. Adetona, Ge Wang, Ayorinde O. Nejo

et al.

Research Square (Research Square), Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 29, 2024

Abstract Investigation of the commercially available Na1.3Al0.3Ti1.7(PO4)3 (NATP) solid electrolyte for Na-ion solid-state batteries (SIBs) application requires a comprehensive understanding its microstructural, thermal behaviour and electrical properties. In this study, we investigated properties NATP through different spectroscopic techniques, including XRD, SEM, DSC/TGA, Dilatometer, Impedance Spectroscopy. The impact sintering temperature on densification, microstructural was investigated. Both Archimedes geometric density measurement methods were utilised to determine relative (ρr) sintered ceramics. Additionally, optimum at which AlPO4 secondary phase is suppressed/minimised electrolyte. Refinement phases present in studied using Topas 5 software provide insight into crystalline structure ceramic. ionic conductivity studies found be range 10− 7 – 8 S/cm 25°C, activation energies 0.46 ± 0.35 eV. This study provides thorough properties, indicating potential as

Language: Английский

Citations

0