Materials Horizons,
Journal Year:
2024,
Volume and Issue:
11(9), P. 2131 - 2142
Published: Jan. 1, 2024
A
novel
solvent–exchange-assisted
wet-stretching
strategy
is
proposed
to
prepare
anisotropic
PVA
hydrogels
by
tuning
the
macromolecular
chain
movement
and
optimizing
polymer
network.
These
exhibit
excellent
mechanical
properties.
Advanced Functional Materials,
Journal Year:
2021,
Volume and Issue:
31(42)
Published: July 20, 2021
Abstract
Inspired
by
the
human
skin,
electronic
skins
(e‐skins)
composed
of
various
flexible
sensors,
such
as
strain
sensor,
pressure
shear
force
temperature
and
humility
delicate
circuits,
are
emerged
to
mimic
sensing
functions
skins.
In
this
review,
strategies
realize
versatile
functionalities
natural
skin‐like
e‐skins,
including
strain‐,
pressure‐,
force‐,
temperature‐
humility‐sensing
abilities,
well
self‐healing
ability
other
summarized.
Some
representative
examples
high‐performance
e‐skins
their
applications
outlined
discussed.
Finally,
outlook
future
is
presented.
Small,
Journal Year:
2021,
Volume and Issue:
18(7)
Published: Nov. 25, 2021
Abstract
Multiresponsive
flexile
sensors
with
strain,
temperature,
humidity,
and
other
sensing
abilities
serving
as
real
electronic
skin
(e‐skin)
have
manifested
great
application
potential
in
flexible
electronics,
artificial
intelligence
(AI),
Internet
of
Things
(IoT).
Although
numerous
sole
function
already
been
reported
since
the
concept
e‐skin,
that
mimics
features
human
skin,
was
proposed
about
a
decade
ago,
ones
more
capacities
new
emergences
are
urgently
demanded.
However,
highly
integrated
sensitive
multiresponsive
functions
becoming
big
thrust
for
detection
body
motions,
physiological
signals
(e.g.,
blood
pressure,
electrocardiograms
(ECG),
electromyograms
(EMG),
sweat,
etc.)
environmental
stimuli
light,
magnetic
field,
volatile
organic
compounds
(VOCs)),
which
vital
to
real‐time
all‐round
health
monitoring
management.
Herein,
this
review
summarizes
design,
manufacturing,
presents
future
challenges
fabricating
these
next‐generation
e‐skin
wearable
electronics.
Journal of Materials Chemistry A,
Journal Year:
2021,
Volume and Issue:
9(34), P. 18406 - 18420
Published: Jan. 1, 2021
Herein,
the
preparation
of
a
highly
tough,
freezing-tolerant,
healable
and
thermoplastic
starch/poly(vinyl
alcohol)
organohydrogel
for
flexible
electronic
devices
is
presented.
Advanced Functional Materials,
Journal Year:
2023,
Volume and Issue:
33(15)
Published: Feb. 7, 2023
Abstract
The
conductive
hydrogels
always
suffered
from
high
internal
friction,
large
hysteresis,
and
low
capability
of
accurately
predicting
physical
deformation,
which
seriously
restricted
their
application
in
smart
wearable
devices.
To
address
these
problems,
solvent
molecules
are
directionally
inserted
into
the
polymer
molecule
chains
via
bridge
effect
to
effectively
reduce
molecular
friction.
Moreover,
swelling
is
also
combined
eliminate
temporary
entanglements
hydrogel
system.
cooperation
between
swollen
endows
prepared
polyacrylamide
(PAM)/laponite/H
3
BO
/ethylene
glycol
(Eg)
organohydrogel
(PLBOH)
ultralow
hysteresis
(1.38%,
ε
=
100%),
ultrafast
response
(≈10
ms),
linearity
whole‐strain‐range
(
R
2
0.996)
with
a
great
sensitivity
GF
2.68
at
strain
range
0–750%).
Meanwhile,
PL
10
B
30
OH
exhibits
long‐term
stability,
excellent
stretchability,
dissipated
energy.
Furthermore,
assembled
triboelectric
nanogenerator
(TENG)
displays
an
outstanding
energy
harvesting
performance
output
voltage
200
V
size
20
mm
×
mm.
sensors
can
monitor
small
facial
expressions
human
movements,
indicating
tremendous
applications
self‐powered
intelligent
flexible
electronics
under
harsh
environmental
conditions.
Journal of Materials Chemistry A,
Journal Year:
2021,
Volume and Issue:
9(40), P. 23243 - 23255
Published: Jan. 1, 2021
A
wearable
multifunctional
sensor
was
proposed,
consisting
of
strain
and
temperature
sensors,
both
which
were
fabricated
by
a
rationally
designed
toughness
conductive
organohydrogel.
Materials Horizons,
Journal Year:
2022,
Volume and Issue:
9(5), P. 1356 - 1386
Published: Jan. 1, 2022
Organohydrogels
are
attractive
for
constructing
various
flexible
devices
with
good
environmental
tolerance
and
smart
materials.
Their
significant
developments
in
preparation,
performance
optimization
application
systematically
reviewed.
Chemistry of Materials,
Journal Year:
2022,
Volume and Issue:
34(3), P. 1065 - 1077
Published: Jan. 21, 2022
Ionic
hydrogels
hold
substantial
promise
as
soft
materials
for
achieving
versatile
wearable
ionotronics
due
to
the
integrated
merits
of
appropriate
mechanical
properties,
excellent
conductivity,
and
good
conformability.
However,
overcoming
freezing
at
subzero
temperatures
hindering
evaporation
water
are
still
huge
challenges
ionic
hydrogels.
Herein,
a
dual-cross-linked
ionohydrogel
was
designed
using
Al3+
cross-link
with
polymer
network
through
dynamic
metal
coordination
bonds
in
liquid
(IL)
binary
solvent
system,
allowing
properties
(∼1
MPa,
∼600%),
transparency
(>90%),
high
conductivity
(∼12.40
mS
cm–1),
robust
adhesion,
along
advantages
superior
antifreezing
long-term
antidehydration
properties.
These
exceptional
characteristics
inspired
us
fabricate
dual-responsive
sensors,
which
could
simultaneously
detect
human
motion
signals
wide
range
change
(from
−30
40
°C)
an
impressive
temperature
coefficient
resistance
(TCR)
value
−0.035
−0.44
°C–1).
More
promisingly,
benefiting
from
interfacial
adhesion
between
poly(dimethylsiloxane)
(PDMS)
ionohydrogels,
triboelectric
nanogenerator
assembled
single-electrode
mode
that
capable
providing
sustainable
energy
ionotronic
devices
even
temperatures.
This
work
opens
up
effective
strategy
design
multifunctional
ionohydrogel,
enabling
various
applications
into
single
device.
Small,
Journal Year:
2021,
Volume and Issue:
17(24)
Published: May 19, 2021
Abstract
Hydrogel‐based
electronics
have
found
widespread
applications
in
soft
sensing
and
health
monitoring
because
of
their
remarkable
biocompatibility
mechanical
features
similar
to
human
skin.
However,
they
are
subjected
potential
challenges
like
structural
failure,
functional
degradation,
device
delamination
practical
applications,
especially
facing
extreme
environmental
conditions
(e.g.,
abnormal
temperature
humidity).
To
address
these,
ionically
conductive
organohydrogel‐based
developed,
which
can
perform
at
subzero
elevated
temperatures
(thermal
compatibility)
as
well
dehydrated
hydrated
environments
(hydration
for
extended
applications.
More
specifically,
gelatin/poly(acrylic
acid–
N
‐hydrosuccinimide
ester)
(PAA–NHS
ester)‐based
ionic‐conductive
organohydrogel
is
synthesized.
By
introducing
a
glycerol–water
binary
solvent
system,
the
gel
maintain
softness
wide
range
(from
−80
60
°C).
Besides,
excellent
conductivity
achieved
under
various
by
soaking
into
lithium
chloride
anhydrous
(LiCl)
solution.
Strong
adhesion
with
skin,
even
water,
be
realized
covalent
bonds
between
NHS
ester
from
amino
groups
The
performances
LiCl‐loaded
PAA‐based
(L‐PAA‐OH)‐based
further
demonstrated
freezing
high
underwater
conditions,
unveiling
promising
prospects
wearable
conditions.