Cited by Electron-mediator-free efficient photocatalytic regeneration of coenzyme NAD(P)H via direct electron transfer using ultrathin Bi2MoO6 nanosheets

Recent progress in photocatalytic NAD(P)H regeneration for photocatalytic-enzymatic-coupling system DOI

Wei Lan, Maodi Wang,

Huicong Dai

et al.

Frontiers of Chemical Science and Engineering, Journal Year: 2024, Volume and Issue: 18(4)

Published: March 12, 2024

Language: Английский

Citations

NAD(P)H-Inspired CO₂ Reduction Based on Organohydrides DOI

Wenjin Dong, Chuanjun Wang,

Yutai Zou

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: unknown

Published: March 29, 2024

The conversion of CO2 into value-added chemicals and fuels using stable, cost-effective, eco-friendly metal-free catalysts is a promising technology to mitigate the global environmental crisis. In Calvin cycle natural photosynthesis, reduction (CO2R) achieved cofactor NADPH as reducing agent through 2e–/1H+ or H– transfer. Consequently, inspired by NAD(P)H, series organohydrides with adjustable reducibility show remarkable potential for efficient CO2R. this review, we first summarize photosensitizers NAD(P)H regeneration list representative photoenzyme CO2R system. Then, introduce NAD(P)H-inspired their applications in redox reactions. Furthermore, discuss recent progress breakthroughs utilizing catalysts. Moreover, delve reaction mechanisms these organohydrides, shedding light on sustainable alternatives metal-based Finally, offer insights prospects directions advancing intriguing avenue organohydride-based

Language: Английский

Citations

In situ NADH regeneration coupled to enzymatic CO2 reduction: from fundamental concepts to recent advances DOI

Neha Gupta, Arpita Sarkar, Soumya Kanti Biswas

et al.

Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 116657 - 116657

Published: April 1, 2025

Language: Английский

Citations

Metalated carbon nitride with facilitated electron transfer pathway for selective NADH regeneration and photoenzyme-coupled CO2 reduction DOI

Pengye Zhang,

Wenjin Dong, Yuanyuan Zhang

et al.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2023, Volume and Issue: 54, P. 188 - 198

Published: Nov. 1, 2023

Language: Английский

Citations

Efficient and Recyclable Photobiocatalytic System via Cofactor Regeneration for Chiral Aryl Alcohol Synthesis DOI

Chun-Xian Cai,

Zi‐Wen Zhou,

Chunxiu Liu

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2023, Volume and Issue: 12(1), P. 37 - 47

Published: Dec. 18, 2023

Integrating efficient enzyme catalysis and sustainable photocatalysis is considered an eco-friendly promising approach for substance conversion. In this work, employing a highly selective ketoreductase metal-free photocatalyst covalent organic framework (COF), we rationally constructed coimmobilized biocatalyzed artificial photosynthesis system mediated by cofactor regeneration chiral alcohol synthesis. COFs (denoted as TTA-T0 TTA-T2) were rapidly fabricated at moderate condition comparative studies, demonstrating that donor–acceptor (D–A) structural TTA-T2 possessed superior photochemical activity virtue of intramolecular charge transfer. With 98.3% yield NADH in 40 min, was applied to cascade NADH-dependent ChKRED20 the asymmetric reduction acetophenone, providing (R)-1-phenylethanol excellent enantioselectivity (ee > 99%). Further, into green matrix achieve protection well convenient recycling both enzyme. After optimizing loading amount other parameters, achieved satisfactory compatibility reusability, with more than 75% photobiocatalytic remaining after four batches operation. This work highlights potential advantages tailorable photocatalysts, strategy coimmobilizing enzymes photocatalysts could be extended solar-driven fine chemical production further development photosynthesis.

Language: Английский

Citations

Highly efficient photoenzymatic CO2 reduction via integrated structural design of porphyrin covalent organic framework on Ti3C2T (MXene) DOI

Zhipeng Huang, Shuli Bai,

Ping Wei

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132943 - 132943

Published: April 1, 2025

Language: Английский

Citations

Principles, applications and future prospects in photodegradation systems DOI

Walied A.A. Mohamed, Aiyeshah Alhodaib, Hanan A. Mousa

et al.

Nanotechnology Reviews, Journal Year: 2025, Volume and Issue: 14(1)

Published: Jan. 1, 2025

Abstract Photocatalytic materials have emerged as pivotal in addressing global challenges such environmental pollution, energy scarcity, and industrial sustainability. This review delves into the principles, mechanisms, applications of photocatalytic systems, emphasizing their roles photodegradation renewable production. United Nations (UN) specified a guideline for sustainable development strategies. UN determined 17 goals services underwent 4 these to reflect distinguishable interest importance different many fields various purposes. Advances material design, nanotechnology, system integration significantly advanced this field, aligning it with goals. Key like TiO 2 , ZnO, g-C 3 N quantum dots are highlighted unique properties enhanced activity through modifications doping, heterostructure formation, biopolymer-supported photocatalysts. Practical wastewater treatment, hydrogen production, air purification, carbon dioxide reduction comprehensively analyzed, case studies demonstrating successful pollutants. The also explores photocatalysis sources, charge carrier recombination photocatalyst stability. Interdisciplinary approaches, including computational modeling machine learning, discussed designing next-generation photocatalysts, innovations sustainability initiatives.

Language: Английский

Citations

Bioinspired photoelectrochemical NADH regeneration based on a molecular catalyst-modified photocathode DOI

Meng Chen, Fengyu Liu, Yizhou Wu

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(24), P. 3319 - 3322

Published: Jan. 1, 2024

Photoelectrochemical NADH regeneration was achieved by a photocathode modified an electron transport mediator and catalyst.

Language: Английский

Citations

Surface Reorganization of Transition Metal Dichalcogenide Nanoflowers for Efficient Electrochemical Coenzyme Regeneration DOI

Nicholas Williams,

Karley Hahn,

Ryan Goodman

et al.

ACS Applied Materials & Interfaces, Journal Year: 2023, Volume and Issue: 15(3), P. 3925 - 3933

Published: Jan. 11, 2023

In the past 20 years, enzymatic conversions have been intensely examined as a practical and environmentally friendly alternative to traditional organocatalytic for chemicals pharmaceutical intermediate production. Out of all commercial enzymes, more than one-fourth are oxidoreductases that operate in tandem with coenzymes, typically nicotinamide adenine dinucleotide (NADH) or phosphate (NADPH). Enzymes utilize coenzymes source electrons, protons, holes. Unfortunately, can be exorbitant; thus, recycling is paramount establishing sustainable affordable cell-free catalyst system. Herein, cost-effective transition metal dichalcogenides (TMDCs), 2H-MoS2, 2H-WS2, 2H-WSe2, were employed first time direct electrochemical reduction NAD+ active form NADH (1,4-NADH). Of three TMDCs, 2H-WSe2 shows optimal activity, producing 1,4 at rate 6.5 μmol cm-2 h-1 faradaic efficiency 45% -0.8 V vs Ag/AgCl. Interestingly, self-induced surface reorganization process was identified, where native oxide grown air spontaneously removed process, resulting activation TMDCs.

Language: Английский

Citations

Constructing a CdS QDs/silica gel composite with high photosensitivity and prolonged recyclable operability for enhanced visible-light-driven NADH regeneration DOI

Chunhui Gao, Shiming Zhang,

Fang‐Fang Feng

et al.

Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 652, P. 1043 - 1052

Published: Aug. 14, 2023

Language: Английский

Citations