Glutathione-Coated Gold Nanoparticles Enabling Bifunctional Therapy at the Buried Interface for Efficient and UV-Resistant Perovskite Solar Cells DOI

Baohua Zhao,

Teng Zhang,

Chenhao Song

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(31), P. 41684 - 41693

Published: July 26, 2024

Very recently, the poor contact between perovskite and carrier selective layer has been regarded as a critical issue for improving performance stability of solar cells (PSCs). In this study, buried interface regularly structured PSCs targeted. Glutathione-coated gold nanoparticles (GSH-AuNPs) are used double-sided passivating agents to improve quality films. It demonstrated that GSH-AuNPs interact strongly with SnO2 underlayer upper layer, significantly reducing defect densities interface. Thus, power conversion efficiency (PCE) can be increased from 20.46% (control, 19.38%, IPCE corrected) 22.22% (GSH-AuNPs modified, 21.10%, notable enhancement in Voc FF. Moreover, strong interaction C═O groups undercoordinated Pb2+ species films inhibits formation metallic Pb0. As result, unencapsulated GSH-AuNPs-modified devices retained 80% their initial PCEs after 1000 h at ambient conditions, relative humidity (RH) 60 ± 5%. UV-resistant have also introducing GSH-AuNPs. Therefore, our findings demonstrate bidirectional therapy strategy feasible approach achieving efficient PSCs.

Language: Английский

A Review on Interface Engineering of MXenes for Perovskite Solar Cells DOI Creative Commons
Srikanta Palei, G. Murali,

Choong‐Hee Kim

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)

Published: May 9, 2023

Abstract With an excellent power conversion efficiency of 25.7%, closer to the Shockley–Queisser limit, perovskite solar cells (PSCs) have become a strong candidate for next-generation energy harvester. However, lack stability and reliability in PSCs remained challenging commercialization. Strategies, such as interfacial structural engineering, more critical influence on enhanced performance. MXenes, two-dimensional materials, emerged promising materials cell applications due their metallic electrical conductivity, high carrier mobility, optical transparency, wide tunable work function, superior mechanical properties. Owing different choices transition elements surface-terminating functional groups, MXenes possess feature tuning which is essential metric band alignment between absorber layer charge transport layers extraction collection PSCs. Furthermore, adopting respective components helps reduce recombination resistance provides smooth transfer paths, leading conductivity operational This review paper aims provide overview components, classified according roles additives (into layer, layers, electrodes) themselves alone or significant importance terms device performance stability. Lastly, we discuss present research status future directions toward its use

Language: Английский

Citations

65

Chlorinated-Ti3C2TF as a dual-functional buried interface on SnO2 electron-transporting layers for 25.09% high-performance n–i–p perovskite solar cells DOI

Ji Cao,

Qiaoyun Chen, Wenting Wu

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(10), P. 3454 - 3469

Published: Jan. 1, 2024

Chlorinated-Ti 3 C 2 T F is used as dual functional buried-interface on SnO electron transporting layer for 25.09% high performance n–i–p perovskite solar cells.

Language: Английский

Citations

24

MXene‐Based Energy Devices: From Progressive to Prospective DOI
Samrana Kazim, Chun Huang,

Naveen Harindu Hemasiri

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Feb. 26, 2024

Abstract Every once in a while, revolutionary technological development arises, which leads to significant change the way approach research and push efforts. The appetite for new technology compels society look game‐changing materials, that can transform industry make advances. Sustainable energy production is paramount addressing climate crisis, generation storage play an important role of self‐powered microelectronic devices. 2D MXenes have emerged as promising candidates other applications owing their inherent electrical merits, high specific surface area, tunable properties. Particularly, context additive interfacial materials perovskite solar cell fabrication utilization additives secondary batteries, this review delves into application such protocols nanostructures tailoring toward and, underlying mechanism uncovered. Further, existing challenges direction future MXene‐based harvesters are discussed.

Language: Английский

Citations

18

Strain Engineering Toward High‐Performance Formamidinium‐Based Perovskite Solar Cells DOI
Yuqin Zhou,

Zhihao Guo,

Saif M. H. Qaid

et al.

Solar RRL, Journal Year: 2023, Volume and Issue: 7(19)

Published: July 16, 2023

The power conversion efficiency (PCE) of organic–inorganic halide perovskite solar cells (PSCs) has increased rapidly in recent years, with the certified best single‐junction photovoltaics reaching an astounding PCE 26%. Formamidine (FA)‐based perovskites possess excellent photovoltaic properties and superior thermal stability, establishing them as one most promising materials for light absorption. However, issue phase instability black‐phase formamidinium lead iodide ( α ‐FAPbI 3 ) seriously impeded its commercialization process, strain found films being regarded a significant factor impacting stability PSCs. This article begins by examining sources characterization techniques related to perovskites. Subsequently, it outlines effects on FA‐based presents strategies modify lattice strain. Finally, potential engineering future is discussed. review aims clarify impact perovskite, determine methods enhance device performance, ultimately facilitate these materials.

Language: Английский

Citations

36

New Nanophotonics Approaches for Enhancing the Efficiency and Stability of Perovskite Solar Cells DOI
Pengfei Cheng,

Yidan An,

Alex K.‐Y. Jen

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 36(17)

Published: Oct. 25, 2023

Abstract Over the past decade, power conversion efficiency (PCE) of perovskite solar cells (PSCs) has experienced a remarkable ascent, soaring from 3.8% in 2009 to record 26.1% 2023. Many recent approaches for improving PSC performance employ nanophotonic technologies, light harvesting and thermal management manipulation charge carrier dynamics. Plasmonic nanoparticles arrayed dielectric nanostructures have been applied tailor absorption, scattering, conversion, as well heat dissipation within PSCs improve their PCE operational stability. In this review, it is begin with concise introduction define realm nanophotonics by focusing on nanoscale interactions between surface plasmons or photonic structures. Prevailing strategies that utilize resonance‐enhanced light–matter boosting stability trapping, transportation, perspectives are then elaborated, resultant practical applications, such semitransparent photovoltaics, colored PSCs, smart windows discussed. Finally, state‐of‐the‐art paradigms reviewed, benefits these aesthetic effects energy‐saving character PSC‐integrated buildings highlighted.

Language: Английский

Citations

24

The dawn of MXene duo: revolutionizing perovskite solar cells with MXenes through computational and experimental methods DOI
Sathish Marimuthu, Arunkumar Prabhakaran Shyma,

Shriswaroop Sathyanarayanan

et al.

Nanoscale, Journal Year: 2024, Volume and Issue: 16(21), P. 10108 - 10141

Published: Jan. 1, 2024

Through increased conductivity, customised surface groups, and mechanical strength, MXene improves perovskite solar cell efficiency stability. Experimental computer modelling optimise MXene's addition in PSC layers, guiding future study.

Language: Английский

Citations

8

MXene-based materials for efficient applications in perovskite solar cells: A review DOI
Yue Li,

Yuhua Wang,

Zichao Xu

et al.

Journal of Material Science and Technology, Journal Year: 2024, Volume and Issue: 215, P. 214 - 232

Published: July 29, 2024

Language: Английский

Citations

7

Two-dimensional MXenes: A route from synthesis to applications in self-powered IoT devices DOI
Muhammad Ahsan Saeed, Muhammad Zain Qamar,

Zubair Khalid

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 490, P. 151600 - 151600

Published: April 23, 2024

Language: Английский

Citations

6

Defect Engineering at Buried Interface of Perovskite Solar Cells DOI
Mohamad Firdaus Mohamad Noh,

Nurul Affiqah Arzaee,

Muhammad Najib Harif

et al.

Small Methods, Journal Year: 2024, Volume and Issue: unknown

Published: June 21, 2024

Abstract Perovskite solar cells (PSC) have developed rapidly since the past decade with aim to produce highly efficient photovoltaic technology at a low cost. Recently, physical and chemical defects buried interface of PSC including vacancies, impurities, lattice strain, voids are identified as next formidable hurdle further advancement performance devices. The presence these has unfavorably impacted many optoelectronic properties in PSC, such band alignment, charge extraction/recombination dynamics, ion migration behavior, hydrophobicity. Herein, broad but critical discussion on various essential aspects related is provided. In particular, existing surface underlying transporting layer (CTL) bottom perovskite film initially elaborated. situ ex characterization approaches adopted unveil hidden elucidated determine their influence efficiency, operational stability, photocurrent–voltage hysteresis PSC. A myriad innovative strategies defect management CTL, introduction passivation materials, strain engineering, morphological control used address also systematically catalyze development more efficient, reliable, commercially viable

Language: Английский

Citations

5

High-performance self-powered perovskite photodetectors enabled by Nb2CTx-passivated buried interface DOI
Shareen Shafique, Akeel Qadir,

Taimoor Iqbal

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1004, P. 175903 - 175903

Published: Aug. 6, 2024

Language: Английский

Citations

5