Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 665, P. 945 - 957
Published: March 29, 2024
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 665, P. 945 - 957
Published: March 29, 2024
Language: Английский
Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 146207 - 146207
Published: April 1, 2025
Language: Английский
Citations
0Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 111191 - 111191
Published: April 1, 2025
Language: Английский
Citations
0Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)
Published: April 10, 2025
The efficient electrochemical CO2 reduction to C2+ products at high current densities remains a significant challenge. Here we show inherently hydrophobic and hierarchically porous Cu supraparticles comprising sub-10 nm constituent particles for ampere-level CO2-to-C2+ electrosynthesis. These feature abundant grain boundaries selectivity, coupled with interconnected mesopores interparticle macropore cavities enhance the accessibility of active sites mass transfer, breaking trade-off between activity transfer in Cu-based catalysts. Moreover, intrinsic hydrophobicity mitigates water-flooding issue catalytic layer flow cells, improving stability densities. Consequently, achieve electrolysis up 3.2 A cm-2 Faradaic efficiency 74.9% (compared 1.21 55.4% nanoparticles) maintain 1 over 100 h. This work provides profound insights into effect coupling reaction under presents corresponding solution by superstructure design.
Language: Английский
Citations
0Small, Journal Year: 2025, Volume and Issue: unknown
Published: May 2, 2025
Abstract CO 2 reduction reaction (CO RR) has attracted considerable attention as a sustainable approach for carbon capture and conversion. However, the dynamic nature of electrocatalysts under operational conditions, particularly at interface, presents significant challenges understanding mechanisms optimizing catalyst design. In situ/operando characterization techniques are crucial to interfaces RR. This review focuses on various in employed explore interfaces, insights derived from these studies, their implications
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 665, P. 945 - 957
Published: March 29, 2024
Language: Английский
Citations
3