Journal of Materials Chemistry C,
Journal Year:
2024,
Volume and Issue:
12(24), P. 8794 - 8803
Published: Jan. 1, 2024
The
microwave
absorption
performance
of
(Co
0.2
Mo
V
Nb
Ta
)C
x
high-entropy
carbides
prepared
by
ball
milling
is
optimized
modulating
the
concentration
carbon
vacancies.
Nano-Micro Letters,
Journal Year:
2024,
Volume and Issue:
16(1)
Published: July 12, 2024
Abstract
Broadband
electromagnetic
(EM)
wave
absorption
materials
play
an
important
role
in
military
stealth
and
health
protection.
Herein,
metal–organic
frameworks
(MOFs)-derived
magnetic-carbon
CoNiM@C
(M
=
Cu,
Zn,
Fe,
Mn)
microspheres
are
fabricated,
which
exhibit
flower-like
nano–microstructure
with
tunable
EM
response
capacity.
Based
on
the
MOFs-derived
CoNi@C
microsphere,
adjacent
third
element
is
introduced
into
magnetic
CoNi
alloy
to
enhance
performance.
In
term
of
broadband
absorption,
order
efficient
bandwidth
(EAB)
value
Mn
>
Fe
Zn
Cu
microspheres.
Therefore,
CoNiMn@C
hold
outstanding
EAB
can
reach
up
5.8
GHz
(covering
12.2–18
at
2.0
mm
thickness).
Besides,
off-axis
electron
holography
computational
simulations
applied
elucidate
inherent
dielectric
dissipation
loss.
Rich
heterointerfaces
promote
aggregation
negative/positive
charges
contacting
region,
forming
interfacial
polarization.
The
graphitized
carbon
layer
catalyzed
by
CoNiMn
core
offered
mobility
path,
boosting
conductive
Equally
importantly,
coupling
observed
strengthen
responding
behaviors.
This
study
provides
a
new
guide
build
regulating
ternary
alloy.
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: July 1, 2024
Abstract
Nano‐heterointerface
engineering
has
been
demonstrated
to
influence
interfacial
polarization
by
expanding
the
interface
surface
area
and
constructing
a
built‐in
electric
field
(BEF),
thus
regulating
electromagnetic
(EM)
wave
absorption.
However,
dielectric‐responsive
mechanism
of
BEF
needs
further
exploration
enhance
comprehensive
understanding
polarization,
particularly
in
terms
quantifying
optimizing
strength.
Herein,
“1D
expanded
2D
structure”
carbon
matrix
is
designed,
semiconductor
ZnIn
2
S
4
(ZIS)
introduced
construct
carbon/ZIS
heterostructure.
The
cross‐dimensional
nano‐heterointerface
design
increases
coupling
sites
induces
an
increase
Fermi
level
difference
on
both
sides
modulate
distribution
charges,
thereby
strengthening
at
interface.
synergistic
effect
leads
excellent
EM
absorption
performance
(minimum
reflection
coefficient
RC
min
=
−67.4
dB,
effective
bandwidth
EAB
6.0
GHz)
This
work
introduces
general
modification
model
for
enhancing
inspires
development
new
strategies
functional
materials
with
unique
electronic
behaviors
through
heterointerface
engineering.
ACS Applied Nano Materials,
Journal Year:
2024,
Volume and Issue:
7(3), P. 2702 - 2710
Published: Jan. 19, 2024
With
the
increasing
popularity
of
electronic
communication
equipment,
electromagnetic
pollution
continues
to
worsen,
and
requirement
for
ultrathin,
highly
flexible,
multifunctional
interference
(EMI)
shielding
films
is
becoming
more
imperative.
Within
this
study,
composite
were
prepared
by
introducing
one-dimensional
(1D)
cellulose
nanocrystals
(CNC)
silver
nanowires
(AgNWs)
into
two-dimensional
(2D)
MXene-based
materials
using
method
vacuum-filtration-induced
self-assembly.
Benefiting
from
1D/2D
conductive
network
composed
AgNWs
MXene,
film
has
a
high
conductivity
(36,244
S
m–1)
excellent
EMI
performance
(69.94
dB)
at
thickness
54
μm.
The
introduction
1D
sustainable
CNC
as
"binder"
increased
tensile
strength
16.75
MPa
(pure
Ti3C2Tx
MXene
film)
26.14
MPa.
In
addition,
MXene/AgNWs/CNC
have
outstanding
Joule
heating
performance,
surface
temperature
exceeded
70.2
°C
under
2.5
V.
Moreover,
recyclable
properties,
test
results
indicate
that
SE
value
40.78
dB
after
recycling.
We
believe
designed
promising
applications
with
respect
protection
in
flexible
wearable
devices,
aerospace
systems,
extreme
environments.
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 9, 2024
Abstract
Porous
materials
emerging
as
potential
high‐efficiency
electromagnetic
(EM)
wave
absorbers
confront
a
critical
trade‐off
between
impedance
matching
and
attenuation
capability.
In
this
study,
versatile
strategy
is
reported
to
overcome
challenge
by
constructing
gradient
pores
via
solvent‐assisted
linker
exchange
for
the
fabrication
of
metal‐organic
framework
(MOF)
derived
Fe/Fe
3
Co
7
/Co/C
composites
with
high
porosity.
The
characteristics
single‐pored
gradient‐pored
derivatives
are
investigated
through
combined
experimental
simulation
approaches.
Simulated
space
EM
field,
loss
density,
Smith
charts
reveal
significantly
enhanced
interactions
optimized
within
pores.
Compared
individual
MOF
derivatives,
derivative
exhibits
improved
from
large‐pored
shell
superior
capability
small‐pored
core,
giving
rise
Pareto
improvement
in
absorption
strong
reflection
(−64.7
dB)
wide
effective
adsorption
bandwidth
(5.8
GHz)
at
thickness
2.5
mm.
This
work
not
only
advances
novel
pore
efficient
capability,
but
also
sheds
light
on
underlying
mechanisms
interaction
varied
porosity,
offering
insights
extended
designs
magnetic,
electric
optic
devices.