Enhanced H2o2 Utilization Efficiency in Ldh Fenton-Like Catalysis System for Highly Efficient Degradation of Diclofenac: Trimetal Cycle-Mediated H2o2 Activation DOI
Ziyan Tan, Yin Xu, Yujiao Wang

et al.

Published: Jan. 1, 2024

Drug residues in water can lead to drug resistance and affect human health the survival of aquatic organisms. Fenton was one most effective wastewater treatment methods, but there were some problems such as poor metal cycling performance catalyst low utilization efficiency H2O2. The ternary layered double hydroxide (LDH) Cu0.6Co2.4Fe-LDH prepared by adjusting molar ratio Cu/Co. employed for efficient degradation diclofenac (DCF) catalytic hydrogen peroxide (H2O2). At a natural pH=6.5 H2O2 =2 mM, removal rate DCF 98.2% (mineralization =72.5%). After 8 cycles, still 77%. Cu0.6Co2.4Fe-LDH/H2O2 system equally suitable antibiotics ciprofloxacin environments. Inorganic ions organic compounds real had little influence on this heterogeneous Fenton-like process. Free radical trapping experiments electron paramagnetic resonance spectra showed that hydroxyl radicals (·OH) played leading role DCF. trimetal cations act synergistically accelerated transfer redox cycle between ions. Simultaneously, calculated compared. dose, increased 71.8%. In paper, proposed improve under condition scant amount H2O2, which provided strategy solving problem oxidants materials reaction systems.

Language: Английский

Application of Fe-MOFs in Photodegradation and Removal of Air and Water Pollutants: A Review DOI Creative Commons
Jun Cai, Peng Yang,

Yanxin Jiang

et al.

Molecules, Journal Year: 2023, Volume and Issue: 28(20), P. 7121 - 7121

Published: Oct. 17, 2023

Photocatalytic technology has received increasing attention in recent years. A pivotal facet of photocatalytic lies the development photocatalysts. Porous metal-organic framework (MOF) materials, distinguished by their unique properties and structural characteristics, have emerged as a focal point research field, finding widespread application photo-treatment conversion various substances. Fe-based MOFs attained particular prominence. This review explores advances degradation aqueous gaseous Furthermore, it delves into interaction between active sites Fe-MOFs pollutants, offering deeper insights mechanism action. Fe-MOFs, photocatalysts, predominantly facilitate pollutant removal through redox processes, with acid sites, formation complexes composite metal elements, binding to unsaturated ligands (CUSs), hydrogen bonding modulate respiratory behavior. also highlights points future research, elucidating challenges opportunities that lie ahead harnessing characteristics advantages Fe-MOF catalysts. In essence, this provides comprehensive summary progress on Fe-MOF-based catalysts, aiming serve guiding reference for other catalytic processes.

Language: Английский

Citations

11

Nano-photosensitizers with gallic acid-involved Fe–O–Cu “electronic storage station” bridging ligand-to-metal charge transfer for efficient catalytic theranostics DOI

Yunlong Li,

Chunsheng Li, Shuang Liu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 676, P. 974 - 988

Published: July 24, 2024

Language: Английский

Citations

4

Strategies for Improving Performance of Iron-Based Catalysts in Activating Heterogeneous Fenton-Like Oxidation in Pollutants Degradation: From the Perspective Of Materials Structure Design DOI

Guorong Xu,

Qian Liu, Zhaohuan Mai

et al.

Process Safety and Environmental Protection, Journal Year: 2024, Volume and Issue: 190, P. 794 - 820

Published: Aug. 27, 2024

Language: Английский

Citations

4

Fenton-like catalytic MOFs driving electrochemical aptasensing toward tracking lead pollution in pomegranate fruit DOI
Wenjie Lu,

Xiaoli Dai,

Renchun Yang

et al.

Food Control, Journal Year: 2024, Volume and Issue: 169, P. 111006 - 111006

Published: Nov. 12, 2024

Language: Английский

Citations

4

A Dual-Mode Sensor Based on Surface Molecularly Imprinted Metal-Organic Frameworks for the Highly Accurate and Selective Detection of Tetracycline DOI
Lu Zhang,

Mingping Shen,

Zongda Li

et al.

Sensors and Actuators B Chemical, Journal Year: 2025, Volume and Issue: unknown, P. 137445 - 137445

Published: Feb. 1, 2025

Language: Английский

Citations

0

Cu-doped MIL-101(Fe) with unsaturated metal sites activate peroxymonosulfate for efficient degradation of ciprofloxacin: Optimization, mechanism, and toxicity assessment DOI
Yuxin Huang,

Liwen Tang,

Rui‐Xiang Hu

et al.

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114181 - 114181

Published: Feb. 1, 2025

Language: Английский

Citations

0

Synthesis of (Fe0.2Co0.2Ni0.2Cu0.2Mn0.2)Fe2O4 High Entropy Spinel Oxide for Photo-Fenton Degradation of Oxytetracycline Hydrochloride Over a Wide pH Range DOI

Yuxin Gan,

Dan Liu,

Zhipu Wang

et al.

Catalysis Letters, Journal Year: 2025, Volume and Issue: 155(4)

Published: March 1, 2025

Language: Английский

Citations

0

Enhanced photo-Fenton catalysis via bandgap engineering of metalloporphyrin-based covalent organic framework shells on bimetallic metal–organic frameworks: accelerating Fe(iii)/Fe(ii) loop activation DOI
Hui Wang, Xuefeng Zhang, Xiang‐Feng Wu

et al.

Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A metallized porphyrin-based COF shell was constructed on bimetal based NH 2 -Cu/Fe-MIL-101 nanoparticles, which demonstrates exceptional photo-Fenton catalytic efficiency and excellent stability.

Language: Английский

Citations

0

Biomass Cellulose-Derived Carbon Aerogel Supported Magnetite-Copper Bimetallic Heterogeneous Fenton-like Catalyst Towards the Boosting Redox Cycle of ≡Fe(III)/≡Fe(II) DOI Creative Commons
Qiang Zhao,

Jiawei Yang,

Jiayi Xia

et al.

Nanomaterials, Journal Year: 2025, Volume and Issue: 15(8), P. 614 - 614

Published: April 16, 2025

To degrade high-concentration and toxic organic effluents, we developed Fe-Cu active sites loaded on biomass-source carbon aerogel (CA) to produce a low-cost high-efficiency magnetic Fenton-like catalyst for the catalytic oxidative decomposition of pollutants. It exhibits excellent performance in reactions RhB removal at an ultrahigh initial concentration up 1000 ppm. be specific, Fe3O4 Cu nanoparticles are generated situ mesoporous CA support, denoted as Fe3O4-Cu/CA catalyst. Experimentally, factors including dye concentration, dosage, H2O2 pH, temperature, which significantly influence degradation rate RhB, carefully studied. The (1000 ppm) ratio reaches 93.7% within 60 min under low dosage. also shows slight metal leaching (almost 1.4% total Fe 4.0% leached after complete 25 μmol conditions 15 mg 20 mL solution (600 ppm), 200 μL 30 wt% pH 2.5, 40 °C), good activity degrading pollutants, reusability, stability (the is nearly 82.95% 8th cycle reaction). synergistic effect between species plays vital role promoting redox Fe(III)/Fe(II) enhancing generation ·OH. suitable ultrahigh-concentration pollutant practical wastewater treatment applications.

Language: Английский

Citations

0

Construction of a cathodic MOF/FeOOH heterojunction for boosted Fe(Ⅲ) reduction in electro-Fenton processes DOI
Hongwei Zhu,

Xu Yin,

Yi Wang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 362, P. 124770 - 124770

Published: Nov. 1, 2024

Language: Английский

Citations

3