Proton Conducting Metal‐Organic Frameworks (MOFs) via Post Synthetic Transmetallation and Water Induced Structural Transformations

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: 30(49)

Published: June 25, 2024

Post Synthetic Modification (PSM) of Metal-Organic Frameworks (MOFs) is a crucial strategy for developing new MOFs with enhanced functional properties compared to their parent one. PSM can be accomplished through various methods:1) modification organic linkers; 2) exchange metal ions or nodes; and 3) inclusion solvent/guest molecules. Herein, bimetallic monometallic containing biphenyl dinitro-tetra-carboxylates (NCA) are demonstrated. The tetra carboxylate NCA, produces Cd-MOF-1 Cu-MOF-1 CoZn-MOF in solvothermal reactions the corresponding salts. undergoes post-synthetic transmetallation Cd(NO

Language: Английский

Exceptional proton conduction in two robust zirconium(IV)/hafnium(IV)-organic frameworks constructed by tetratopic carboxylate

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1010, P. 177546 - 177546

Published: Nov. 14, 2024

Language: Английский