Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 9, 2024

Abstract Research on organic–inorganic hybrid materials (OIHMs) has experienced explosive growth in the past decades. The diversity of organic components allows for introduction various spatial scales, functional groups, and polarities, while inorganic provide higher hardness, heat resistance, stability, their flexible combination facilitates formation diverse structures. Furthermore, simple cost‐effective synthesis methods, such as room temperature solution processes mechanochemical techniques, enable precise control over materials' properties at different thus achieving adjustable structure–performance relationships. This review will discuss recent research progress OIHMs within field optoelectronics related optoelectronic device applications. According to dimension nature interface, this divides into four structural categories. ongoing revealed applications fields solar cells, light‐emitting devices, detectors, memristors. As an outlook, potential perovskite 0D metal halide materials, which are currently most studied, enhancing performance stability is discussed.

Language: Английский

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Multiphase Transformation in Hybrid Copper(I)-Based Halides Enable Improved X-ray Scintillation and Real-Time Imaging

ACS Materials Letters, Journal Year: 2024, Volume and Issue: 6(4), P. 1542 - 1548

Published: March 19, 2024

Crystal-glass phase transformation and glass recrystallization in zero-dimensional (0D) hybrid metal halides make them thriving X-ray scintillators with the advantages of large-area fabrication improved performance. Herein, we report three 0D copper(I) composed identical organic cations versatile self-assembly copper-iodide anions find that volumes inorganic groups are related to their lattice energies, which conformationally governed thermodynamics formation through destabilization. A subsequent heating counterparts allows bulk glass-ceramic via recrystallization, exhibiting outstanding scintillation performances (with a light yield 64 000 ph MeV–1 detection limit 72.6 nGy s–1) high stability for real-time imaging (spatial resolution above 20 lp mm–1). This multiphase strategy luminescence halide opens an exploratory way structural design engineering scintillator screens imaging.

Language: Английский

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Unlocking the Potential of Organic‐Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 5, 2024

Organic-inorganic hybrid manganese(II) halides (OIMnHs) have garnered tremendous interest across a wide array of research fields owing to their outstanding optical properties, abundant structural diversity, low-cost solution processibility, and low toxicity, which make them extremely suitable for use as new class luminescent materials various optoelectronic applications. Over the past years, plethora OIMnHs with different dimensionalities multifunctionalities such efficient photoluminescence (PL), radioluminescence, circularly polarized luminescence, mechanoluminescence been newly created by judicious screening organic cations inorganic Mn(II) polyhedra. Specifically, through precise molecular engineering, series near-unity PL quantum yields, high anti-thermal quenching excellent stability in harsh conditions devised explored applications light-emitting diodes (LEDs), X-ray scintillators, multimodal anti-counterfeiting, fluorescent sensing. In this review, latest advancements development are summarized, covers from fundamental physicochemical properties advanced applications, an emphasis on functionality design especially LEDs detection imaging. Current challenges future efforts unlock potentials these promising also envisioned.

Language: Английский

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Emerging 0D Hybrid Metal Halide Luminescent Glasses

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

0D hybrid metal halide (HMH) luminescent glasses have garnered significant attentions for its chemical diversity in optoelectronic applications and it also retains the skeleton connectivity coordination mode of crystalline counterparts while exhibiting various physics/chemistry characteristics distinct from states. However, understanding glass-forming ability specific structural origins underpinning properties HMH remains elusive. In this review, is started solid-liquid phase transition thermodynamic analysis HMHs formed through melt-quenching, summarize current compounds capable stably forming glassy phases via design. The characterization methods are further discussed highlight exceptional transparency, properties, glass crystallization behaviors. Moreover, application prospects demonstrated by these been presented accordingly X-ray detection imaging, anti-counterfeiting, information encryption. Finally, perspective offered into future development emerging family their applications.

Language: Английский

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Guanidinium‐Based Manganese(II) Bromide with High Glass‐Forming Ability for Thermoplastic Curved X‐ray Imaging

Laser & Photonics Review, Journal Year: 2024, Volume and Issue: 18(7)

Published: Feb. 25, 2024

Abstract The development of large‐area transparent organic‐inorganic hybrid metal halide (OIMH) scintillation screens is restricted by the anisotropic single‐crystal growth, numerous grain boundaries in polycrystalline wafers, and inhomogeneous dispersion perovskite‐polymer composite films. crystal‐glass phase transition OIMH materials may provide a promising solution for above significant challenges. Herein, new class amorphous guanidinium‐based manganese bromide glasses, (DPG) 2 MnBr 4 (DOTG) (DPG = 1,3‐diphenylguanidinium, DOTG 1,3‐di‐o‐tolylguanidinium), are synthesized through low‐temperature melt‐quenching process. shows impressive glass‐forming ability because large viscosity ( η ) at melting temperature T m 3426 mPa·s) small fragility index 52.35), which can be potential glass scintillator. (e.g., 13 cm × cm) scintillator high light transmittance > 80%, low detection limit 237.3 nGy s −1 X‐ray imaging spatial resolution 12 lp mm . Interestingly, < 40 °C gives unique thermoplastic properties, allowing it to conform irregularly shaped objects reduce distortion imaging.

Language: Английский

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Phosphor-converted light-emitting diodes in the marine environment: Current status and future trends

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The exploitation and utilization of resources in marine environments have ignited a demand for advanced illumination optical communication technologies. Light-emitting diodes (LEDs), heralded as "green lighting sources", offer compelling solution to the technical challenges exploration due their inherent advantages. Among myriad LED technologies, phosphor-converted light-emitting (pc-LEDs) emerged frontrunners applications. At heart pc-LEDs lie phosphor materials, colour-converters that orchestrate emission light. In environment, blue-green light with wavelength 440-570 nm exhibits deepest penetration depth, while other wavelengths are rapidly attenuated shallow layer. Additionally, specific crucial particular However, moist environment well continuous stable pose formidable challenge environmental stability phosphors. Therefore, developing phosphors exceptional colour purity high thermal moisture is paramount Herein, this review delves into application pc-LED technology underwater fishery, exploring development strategies tailored environment. insights presented serve valuable reference further research on devices.

Language: Английский

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Crystal structure of (4-fluorobenzyl)triphenylphosphonium chloride, C₂₅H₂₁ClFP

Zeitschrift für Kristallographie - New Crystal Structures, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 22, 2025

Abstract C 25 H 21 ClFP, monoclinic, P 2 1 / n (no. 14), a = 9.5700(2) Å, b 13.9963(2) c 15.8793(4) β 101.024(2)°, V 2087.70(8) Å 3 , Z 4, R gt ( F ) 0.0401, wR ref 0.1112, T 150 K.

Language: Английский

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Organic–Inorganic Hybrid Mn‐Based Transparent Glass for Curved X‐Ray Scintillation Imaging

Advanced Optical Materials, Journal Year: 2023, Volume and Issue: 12(11)

Published: Dec. 25, 2023

Abstract The current mainstream planar X‐ray imaging techniques face significant challenges for accurately capturing the internal structure of curved objects, since variable distances between objects and flat‐panel scintillation screen cannot eliminate distortion in imaging. Though large‐area transparent screens are much more desirable. Here, organic–inorganic hybrid Mn‐based single crystals ([CH 3 Ph P] 2 MnX 4 , X = Cl, Br, I) exhibiting high photoluminescence quantum yield (PLQY) low melting temperature have been employed to prepare glass application through a low‐temperature strategy. [CH MnBr ‐glass shows PLQY (47.8%), high‐resolution performance (12.3 lp mm −1 ), limit detection (25.33 nGy s impressive irradiation stability (102 Gy). Furthermore, high‐contrast at dose (6.865 µGy per exposure, 14.5 times lower than chest radiograph) is achieved. Based on transition ( T g 53.6 °C) easy‐shapeable properties scintillator, with series sizes Φ 2×4 – 8×4 cm can be easily fabricated show quality. These findings provide paradigm future research shapeable scintillators, unlocking new possibilities 3D

Language: Английский

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Bisphosphonium Cation Based Metal Halide Glass Scintillators with Tunable Melting Points

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Organic-inorganic metal halide (OIMH) glass offers the advantages of large-scale production, high transparency, and minimal light scattering. However, undesired crystallization in OIMH can occur, leading to deteriorated transparency. Herein, a series bisphosphonium organic cations were designed construct Mn-based crystals with photoluminescence quantum yield (PLQY) near unity, alongside development highly thermally stable glasses. Two strategies employed lower melting point OIMH: alkyl chain elongation fluorine substitution. The (Hex-3,4-2F)MnBr

Language: Английский

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Crystal structure of (4-bromobenzyl)triphenylphosphonium bromide ethanol solvate, C₅₂H₄₈Br₄OP₂

Zeitschrift für Kristallographie - New Crystal Structures, Journal Year: 2024, Volume and Issue: 239(3), P. 495 - 496

Published: March 25, 2024

Abstract C 52 H 48 Br 4 OP 2 , orthorhombic, Pccn (no. 56), a = 20.173(5) Å, b 12.224(3) c 18.858(5) V 4650.2(19) Å 3 Z 4, R gt ( F ) 0.0395, wR ref 0.0906, T 289(2) K.

Language: Английский

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