Holzforschung,
Journal Year:
2024,
Volume and Issue:
78(7), P. 414 - 424
Published: June 6, 2024
Abstract
The
increasing
recognition
of
the
need
for
economically
viable
carbon
materials
in
supercapacitors
has
resulted
a
notable
emphasis
on
utilizing
recycled
biomass
waste
as
precursor
activated
(AC).
This
study
investigates
production
highly
porous
AC
through
vertically
aligned
graphene
nanosheet
arrays
(VAGNAs)
derived
from
bamboo
parenchyma
cells,
type
waste.
focus
lies
manipulating
ratio
alkali
to
during
activation
process.
Elevating
alkali-carbon
augments
specific
surface
area
while
concurrently
reducing
presence
VAGNAs.
Surprisingly,
generated
with
an
four
exhibits
remarkable
capacitance
215
F
g
−1
when
subjected
current
density
0.2
A
.
When
integrated
into
supercapacitor
apparatus,
this
material
demonstrates
energy
11.2
W-hours
per
kilogram
(Wh
kg
)
at
power
50
W
(W
).
Moreover,
it
displays
exceptional
cycling
stability,
maintaining
89.4
%
its
after
undergoing
10,000
cycles
6
M
potassium
hydroxide
electrolyte.
findings
investigation
underscore
potential
cells
sustainable
storage
applications.
ACS Applied Materials & Interfaces,
Journal Year:
2024,
Volume and Issue:
16(44), P. 60404 - 60414
Published: Oct. 24, 2024
Calcium
molybdate
(CaMoO4)
has
recently
garnered
considerable
attention
for
supercapacitors
due
to
its
stable
crystal
structure
and
cost-effective
preparation.
However,
CaMoO4
prepared
by
traditional
processes
still
suffered
from
insufficient
electrochemical
active
sites
poor
electrical
conductivity
so
far,
thus
leading
the
performance
of
CaMoO4-based
being
inferior
state-of-the-art
ones.
nanofibers
with
a
high
specific
surface
area
exhibit
great
potential
their
ability
offer
increased
charge
storage.
Herein,
mesoporous
anchored
Ni
nanoparticles
were
fabricated
via
electrospinning
combined
subsequent
thermal
treatment.
Density
functional
theory
calculation
UV–vis
spectrophotometer
results
show
that
high-spin
state
can
tune
electronic
nanofibers,
decreasing
band
gap
about
0.67
eV.
Electron
paramagnetic
resonance
(EPR)
studies
imply
doping
influences
reducing
oxygen
vacancy
concentration
introducing
hyperfine
structures
associated
spins.
These
result
in
higher
power
energy
density
supercapacitors.
As
result,
capacitance
1253.7
F·g–1
at
current
0.5
A·g–1
an
86%
retention
rate
after
2000
cycles
5
have
been
achieved
Ni0.25Ca0.75MoO4-based
supercapacitor.
Furthermore,
asymmetric
supercapacitor
(ASC)
device
optimized
CaMoO4/Ni//AC
demonstrated
49.43
Wh·kg–1
2700
W·kg–1,
enabling
lightening
red
light-emitting
diode.
The
strategy
might
pave
way
practical
applications
high-power
Holzforschung,
Journal Year:
2024,
Volume and Issue:
78(7), P. 414 - 424
Published: June 6, 2024
Abstract
The
increasing
recognition
of
the
need
for
economically
viable
carbon
materials
in
supercapacitors
has
resulted
a
notable
emphasis
on
utilizing
recycled
biomass
waste
as
precursor
activated
(AC).
This
study
investigates
production
highly
porous
AC
through
vertically
aligned
graphene
nanosheet
arrays
(VAGNAs)
derived
from
bamboo
parenchyma
cells,
type
waste.
focus
lies
manipulating
ratio
alkali
to
during
activation
process.
Elevating
alkali-carbon
augments
specific
surface
area
while
concurrently
reducing
presence
VAGNAs.
Surprisingly,
generated
with
an
four
exhibits
remarkable
capacitance
215
F
g
−1
when
subjected
current
density
0.2
A
.
When
integrated
into
supercapacitor
apparatus,
this
material
demonstrates
energy
11.2
W-hours
per
kilogram
(Wh
kg
)
at
power
50
W
(W
).
Moreover,
it
displays
exceptional
cycling
stability,
maintaining
89.4
%
its
after
undergoing
10,000
cycles
6
M
potassium
hydroxide
electrolyte.
findings
investigation
underscore
potential
cells
sustainable
storage
applications.