Construction of Nonclassical Type-I Heterojunction for Efficient Photodegrading Tetracycline DOI
Huan Yan, Xinhui Lu, Guoqiang Shen

et al.

Industrial & Engineering Chemistry Research, Journal Year: 2024, Volume and Issue: 63(45), P. 19589 - 19599

Published: Nov. 1, 2024

Traditional Type-I heterojunctions, the combination of large- and narrow-bandgap semiconductors, possess a long electron transmission path an electron–hole confinement region, making them not conducive to improving catalytic performance. Hence, few studies about heterostructure combined with large narrow bandgap in chemocatalysis were invested, especially terms reaction mechanism. Herein, (CdS) (hexagonal boron nitride, h-BN) selected as research objects fabricate h-BN/CdS heterojunction by Joule heating ultrafast procedure. Density functional theory (DFT) calculations performed showed that heterojunctions photogenerated electrons (e–) transferred from h-BN CdS, while holes (h+) moved conversely, which is completely different classical heterojunctions. Thus, nonclassical was successfully constructed, proved DFT experimental verification, revealed excellent visible light response photocatalytic degradation ability tetracycline (TC). The optimized exhibited high rate 84.78% under irradiation. Additionally, applicability expanded photodegradation water environments. A materials proposed, opened up new for efficient photocatalysis antibiotic wastewater degradation.

Language: Английский

Metal–organic frameworks for organic transformations by photocatalysis and photothermal catalysis DOI
Hong‐Guang Jin, Pengcheng Zhao, Yunyang Qian

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(18), P. 9378 - 9418

Published: Jan. 1, 2024

Organic transformation by light-driven catalysis, especially, photocatalysis and photothermal denoted as photo(thermal) is an efficient, green, economical route to produce value-added compounds. In recent years, owing their diverse structure types, tunable pore sizes, abundant active sites, metal-organic framework (MOF)-based catalysis has attracted broad interest in organic transformations. this review, we provide a comprehensive systematic overview of MOF-based for First, the general mechanisms, unique advantages, strategies improve performance MOFs are discussed. Then, outstanding examples transformations over introduced according reaction type. addition, several representative advanced characterization techniques used revealing charge kinetics intermediates presented. Finally, prospects challenges field proposed. This review aims inspire rational design development materials with improved catalysis.

Language: Английский

Citations

48
Insights into HKUST-1 Metal-Organic Framework’s Morphology and Physicochemical Properties Induced by Changing the Copper(II) Salt Precursors DOI Open Access

Joanna Klęba,

Kun Zheng, Dorota Duraczyńska

et al.

Materials, Journal Year: 2025, Volume and Issue: 18(3), P. 676 - 676

Published: Feb. 3, 2025

The HKUST-1 metal-organic framework was synthesized using four different copper(II) salt precursors, namely copper nitrate, sulphate, acetate, and chloride, via the solvothermal method with no mixing. Syntheses were conducted without N,N-dimethylformamide to allow for a greener synthesis of MOFs. selected physicochemical properties obtained frameworks determined. yield products changed in order acetate>nitrate>sulfate, while product chloride. materials characterized by means XRD, nitrogen adsorption–desorption at −196 °C, FTIR, XPS, TGA, SEM, DLS. morphology crystallites their significantly affected when precursors used. comparison results already published works allows correlation parameters like temperature, time, mixing, precursor used on final product.

Language: Английский

Citations

0
Innovative Pathways in Zn-Based Metal-Organic Frameworks: Synthesis, Characterization, and Photocatalytic Efficiency for Organic Dye Degradation DOI

Nadhir N.A. Jafar,

Rafid Jihad Albadr,

Waam Mohammed Taher

et al.

Journal of Organometallic Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 123572 - 123572

Published: Feb. 1, 2025

Language: Английский

Citations

0
A novel and universal dual-channel signal amplification aptasensing platform for ultrasensitive and rapid detection of cardiac biomarkers based on the mutual regulation of bimetallic organic framework and silver nanoclusters DOI

Pengfei Fan,

Qianji Li,

Zhengduo Zhang

et al.

Talanta, Journal Year: 2025, Volume and Issue: 288, P. 127745 - 127745

Published: Feb. 16, 2025

Language: Английский

Citations

0
Donor-acceptor mixed-ligand MOF with energy transfer-mediated high-efficiency singlet oxygen generation for boosted organic photosynthesis DOI
Hong‐Guang Jin, Wei Lin, Pengcheng Zhao

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 689, P. 137231 - 137231

Published: March 6, 2025

Language: Английский

Citations

0
Constructing Cu2+ active sites on pyrazole-decorated UiO-66-NH2 with high activity for photocatalytic CO2 reduction to HCOO− DOI

Xin Chen,

Ya‐Yu Zhao,

Meng-Qiang Deng

et al.

Materials Today Chemistry, Journal Year: 2025, Volume and Issue: 46, P. 102712 - 102712

Published: April 19, 2025

Language: Английский

Citations

0
Recent advances and applications of stimuli-responsive nanomaterials for water treatment: A comprehensive review DOI Creative Commons

Iman Salahshoori,

Amirhosein Yazdanbakhsh, Majid Namayandeh Jorabchi

et al.

Advances in Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 333, P. 103304 - 103304

Published: Sept. 27, 2024

Language: Английский

Citations

3
Ionic Porous Organic Polymer as a Visible-Light Photocatalyst: Efficient Heterogeneous Oxidation of Arylmethylene Compounds and Alcohols Using Molecular Oxygen DOI

Ajay Kumar Sahoo,

Sushil Ranjan Bhatta,

Alka Karn

et al.

ACS Applied Polymer Materials, Journal Year: 2024, Volume and Issue: 6(11), P. 6425 - 6436

Published: May 21, 2024

An ionic porous organic polymer (TzTzIPOP)─synthesized from readily accessible 2,5-di(pyridine-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz) and 3,3′,5,5′-tetrakis(bromomethyl)-2,2′,6,6′-tetramethylbiphenyl (TMBB) as the building blocks using Menshutkin reaction for polymerization─is shown to serve an excellent heterogeneous photoredox well photosensitizing catalyst in presence of molecular oxygen. Efficient green sustainable oxidation arylmethylene compounds (C(sp3)–H bonds) alcohols carbonyl is demonstrated under blue LED irradiation conditions TzTzIPOP Mechanistically, oxidations proceed through photoinduced single-electron transfer energy processes involving intermediacy superoxide anion (O2•–) singlet oxygen (1O2), respectively. The recyclable be robust enough permit reactions multiple times (at least 10 cycles) without loss any catalytic activity. that with oxidant conditions, facilitating easy workup, should much relevance industrial processes.

Language: Английский

Citations

2
Porous Organic Polymers (POPs) Based on Acridone as Heterogeneous Photocatalysts for Oxidative Dimerization and Cyclocondensation Reactions DOI
Parag Tamuly,

Ajay Kumar Sahoo,

Navin Yadav

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: unknown

Published: May 22, 2024

Abstract Porous organic polymers (POPs) are emergent tailor‐made materials, which can be accessed by covalent polymerization of diligently designed molecular building blocks in a bottom‐up fashion. Acridone, well‐known chromophore that undergoes intersystem crossing (ISC) with near‐unity quantum yield akin to benzophenone, was structurally elaborated into block and subjected Friedel‐Crafts polyalkylation afford series POPs, namely, Ac‐MePOP , Ac‐OMePOP Ac‐CBPOP . These POPs exhibit remarkable porosity significant absorption the visible region. Of three polymers, highest BET surface area ca. 1027 m 2 /g is shown serve as an excellent heterogeneous photocatalyst for light‐mediated oxidative transformations, is, coupling benzylamines imines cyclocondensation o ‐phenylenediamines aldehydes benzimidazoles under oxygen atmosphere. It further reused several reaction cycles without any loss catalytic activity its stability intact. Mechanistic studies show 1 O serves key reactive species, formed energy transfer from 3 photocatalytic oxidation reactions. The results demonstrate development stable POP materials properties programmed blocks.

Language: Английский

Citations

1
Green Molecular Reactor Boosting the Photocatalytic Aerobic Oxidation of Sulfides in Clean Solvent DOI
Jiaqi Chen, Wei‐Yin Sun, Yue Zhao

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: 16(20)

Published: July 1, 2024

Abstract The synthesis of sulfoxides has long attracted considerable interest due to their pivotal role in organic synthesis, pharmaceutics and environmental protection. Oxidation the corresponding sulfides is recognized as most effective strategy. Traditional oxidation methods, however, fall short growing demands green chemistry. Photocatalytic aerobic thus garnered attention, employing greenest sustainable oxidants—oxygen or air—and sunlight energy source. Nevertheless, these reactions are typically conducted potentially pollutive solvents rather than solvent, water. To facilitate this transformation aqueous phase, molecular reactors that can encapsulate reactants within confined pores photocatalytic have been developed recently. This Concept article summarizes development for provides perspectives design construction reactors.

Language: Английский

Citations

1