Emerging MOFs, COFs, and their derivatives for energy and environmental applications

The Innovation, Journal Year: 2025, Volume and Issue: 6(2), P. 100778 - 100778

Published: Jan. 18, 2025

Traditional fossil fuels significantly contribute to energy supply, economic development, and advancements in science technology. However, prolonged extensive use of has resulted increasingly severe environmental pollution. Consequently, it is imperative develop new, clean, pollution-free sources with high density versatility as substitutes for conventional fuels, although this remains a considerable challenge. Simultaneously, addressing water pollution critical concern. The design, optimization functional nanomaterials are pivotal advancing new solutions pollutant remediation. Emerging porous framework materials such metal-organic frameworks (MOFs) covalent organic (COFs), recognized exemplary crystalline materials, exhibit potential applications due their specific surface area, adjustable pore sizes structures, permanent porosity, customizable functionalities. This work provides comprehensive systematic review the MOFs, COFs, derivatives emerging technologies, including oxygen reduction reaction, evolution hydrogen lithium-ion batteries, remediation carbon dioxide reaction management. In addition, strategies performance adjustment structure-effect relationships these explored. Interaction mechanisms summarized based on experimental discussions, theoretical calculations, advanced spectroscopy analyses. challenges, future prospects, opportunities tailoring presented.

Language: Английский

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Pressure regulated CO₂ electrolysis on two-dimensional Bi₂O₂Se

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A 2D Bi 2 O Se catalyst with low mass loading demonstrates enhanced performance in CO reduction to formate under high pressure. By pressurizing from ambient 40 bar, the selectivity and partial current density increase significantly.

Language: Английский

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Recent advances of metal-organic frameworks and MOF-derived materials based on p-block metal for the electrochemical reduction of carbon dioxide

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 110151 - 110151

Published: June 1, 2024

Language: Английский

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Porous Bi Nanosheets Derived from β-Bi₂O₃ for Efficient Electrocatalytic CO₂ Reduction to Formate

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(32), P. 42109 - 42117

Published: Aug. 1, 2024

The electrochemical CO2 reduction reaction (ECO2RR) is a promising strategy for converting into high-value chemical products. However, the synthesis of effective and stable electrocatalysts capable transforming specified product remains huge challenge. Herein, we report template-regulated preparation Bi2O3-derived nanosheet catalyst with abundant porosity to achieve expectantly efficient CO2-to-formate conversion. resultant porous bismuth (p-Bi) not only exhibited marked Faradaic efficiency formate (FEformate), beyond 91% in broad potential range from −0.75 −1.1 V H-type cell, but also demonstrated an appreciable FEformate 94% at high current density 262 mA cm–2 commercially important gas diffusion cell. State-of-the-art X-ray absorption near edge structure spectroscopy (XANES) theoretical calculation unraveled distinct production performance p-Bi catalyst, which was cocontributed by its smaller size, plentiful structure, stronger Bi–O bond, thus accelerating promoting subsequent formation intermediates. This work provides avenue fabricate bismuth-based catalysts planar morphologies portfolio applications.

Language: Английский

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Transformation of metal-organic frameworks (MOFs) under different factors

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216263 - 216263

Published: Oct. 21, 2024

Language: Английский

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Metal–organic frameworks and their derivatives for the electrochemical CO₂ reduction reaction: insights from molecular engineering

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(32), P. 20578 - 20605

Published: Jan. 1, 2024

Molecular engineering of MOF-based electrocatalysts for the CO 2 RR, computational simulations, and advanced characterization studies are discussed summarized to illustrate correlation between their structure performance.

Language: Английский

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Engineering Conjugation of Covalent Organic Frameworks for Carbon Dioxide Reduction Reaction

ACS Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 18524 - 18534

Published: Dec. 4, 2024

Language: Английский

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Nanoporous Metal–Organic Frameworks for Electroreduction of Nitrogen and Carbon Dioxide: A Review

ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 6, 2024

Language: Английский

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Structure-activity relationship of small organic molecule functionalized Bi-based heterogeneous catalysts for electrocatalytic reduction of CO2 to formate

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 683, P. 1030 - 1040

Published: Jan. 4, 2025

Language: Английский

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Boron-Doped Oxidized Carbon Black Hybridizing Bismuth Oxide for Electrocatalytic CO₂ to Formate at a Large Current Density

Industrial & Engineering Chemistry Research, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 12, 2025

Language: Английский

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