Frontier Electrolytes for Efficient Sodium-Ion Batteries DOI Creative Commons
Xinyu Zhang

Highlights in Science Engineering and Technology, Journal Year: 2024, Volume and Issue: 121, P. 22 - 30

Published: Dec. 24, 2024

The considerable demand for renewable energy sources and the mounting concern about environmental pollution has created a new development opportunity in field of secondary batteries, which can store chemical place electrical energy. In 2010s, attention was drawn to sodium batteries. A sodium-ion battery (SIB) is specific kind that be recharged, given plentiful element on Earth more stable than lithium Consequently, there been growing body research activity this field. This article will describe electrolytes SIBs, significantly contribute electrochemical safety characteristics SIBs. discussed include liquid electrolyte, solid solid-liquid composite electrolyte. most common use an organic solvent comprises salt (NaPF6 or NaClO4) carbonate. electrolyte successfully matched with range anodes cathodes, resulting satisfactory overall performance. Nevertheless, obvious drawback corroding metal electrodes over extended periods potential concerns.

Language: Английский

Ionic covalent organic frameworks-based electrolyte enables fast Na-ion diffusion towards quasi-solid-state sodium batteries DOI
Tianxing Kang, Haoyuan Liu, Jian Cai

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104192 - 104192

Published: March 1, 2025

Language: Английский

Citations

0
Review of biopolymer electrolytes for sustainable Na-based energy storage systems DOI

Pauline Ida Paulsingh,

M. S. Michael

Journal of Applied Electrochemistry, Journal Year: 2025, Volume and Issue: unknown

Published: June 3, 2025

Language: Английский

Citations

0
Synergistic Dual Electrolyte System of LATP and In‐ Situ Solod‐State PDOL System and its Improvement on the Performance of NCM811 Batteries DOI

Jianhua Cao,

Peng Zhang, Ya‐Kun Wang

et al.

Batteries & Supercaps, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 15, 2024

Abstract 1,3‐Dioxolane (DOL) can undergo in‐situ polymerization in batteries to form solid‐state organic electrolyte PDOL. When applied NCM811||Li battery system, PDOL helps optimize the contact and interface stability between electrodes. This study explores effects of with PE separators coated Li1 .3 Al 0.3 Ti 1.7 (PO 4 ) 3 (LATP) on performance batteries. 2,2,2‐trifluoroethyl phosphite (DETFPi), was mixed DOL at a 1 : 35 mass ratio. Then, LiBF used initiate thereby obtained DETFPi‐PDOL after 24 h room temperature. The composite exhibits enhanced ion conductivity (1.59×10 −4 S cm −1 ), high lithium transference number (0.78), wide electrochemical window (4.53 V), critical current density (2.2 mA −2 ). Li||PDOL@LATP||Li shows extremely low overpotential (35 mV) constant stable cycle 500 1.0 . After cycles C, remaining capacity is 153.9 mAh g retention 82.1 % NCM811||PDOL@LATP||Li indicates that LATP coating surface separator plays an important role optimizing DETFPI‐PDOL are effective improving cycling stability, rate performance, state NCM811

Language: Английский

Citations

1
Regulating the Interfacial Performance of All-Solid-State Sodium Batteries Using Lanthanum Substitution in a Na3Zr2Si2PO12 Solid Electrolyte DOI
Shuaishuai Yang, Jiachen Liang,

Jingxin He

et al.

ACS Applied Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 30, 2024

Language: Английский

Citations

1
Coordinated Na+ Diffusion and Multiscale Interfacial Engineering of Polymer Electrolyte for Room‐Temperature Solid Sodium Metal Batteries DOI Open Access
Yuxiang Guo, Jiacheng Liu,

Ahu Shao

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 23, 2024

Abstract Thin‐layer composite polymer electrolytes (CPEs) provide a safer alternative to flammable liquid for all‐solid‐state sodium metallic batteries (ASSMBs) prototyping. However, conventional CPE designs suffer from insufficient ionic conductivities, oxidation upon high‐voltage and uncontrolled dendrite growth. Herein, an interpenetrating approach by incorporating optimized amount of acrylamide (AM) monomers polymerized within polyethylene oxide (PEO) matrix is proposed. The amide groups tangled PEO/poly(acrylamide) (PAM) segments facilitate the NaTFSI salt dissociation through coordination between CO═Na + N─H/TFSI − interactions, meanwhile boosting Na conduction along ethylene chains. Integrated with bacterial cellulose scaffold mechanical reinforcement, membrane reconciles tensile strength, conductance transference number. Robotic‐arm controlled spray coating applies 4,4′‐(Hexafluoroisopropylidene)diphthalic anhydride (6FDA) 1,2‐dibromobenzene (1,2‐DBB) onto opposite sides PEO/PAM‐BC membrane. electron‐withdrawing 6FDA layer promotes NaF‐rich cathode interface 4.74 V tolerance, while electron‐accepting 1,2‐DBB creates NaBr‐rich that mitigates diffusion barrier. In ASSMB configuration, prototype demonstrates 85.4% capacity retention over 500 cycles at room‐temperature wide‐temperature‐range adaptability 0 80 °C. Transmission‐mode X‐ray diffraction reveals reversible lattice breathing paired cathode, which highlights synergistic stabilized interfaces across scales practical design.

Language: Английский

Citations

1
Frontier Electrolytes for Efficient Sodium-Ion Batteries DOI Creative Commons
Xinyu Zhang

Highlights in Science Engineering and Technology, Journal Year: 2024, Volume and Issue: 121, P. 22 - 30

Published: Dec. 24, 2024

The considerable demand for renewable energy sources and the mounting concern about environmental pollution has created a new development opportunity in field of secondary batteries, which can store chemical place electrical energy. In 2010s, attention was drawn to sodium batteries. A sodium-ion battery (SIB) is specific kind that be recharged, given plentiful element on Earth more stable than lithium Consequently, there been growing body research activity this field. This article will describe electrolytes SIBs, significantly contribute electrochemical safety characteristics SIBs. discussed include liquid electrolyte, solid solid-liquid composite electrolyte. most common use an organic solvent comprises salt (NaPF6 or NaClO4) carbonate. electrolyte successfully matched with range anodes cathodes, resulting satisfactory overall performance. Nevertheless, obvious drawback corroding metal electrodes over extended periods potential concerns.

Language: Английский

Citations

0