Natural and Nature‐Inspired Biomaterial Additives for Metal Halide Perovskite Optoelectronics DOI
Jiye Han, Ying Tian, Il Jeon

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 10, 2024

This comprehensive review meticulously categorizes and discusses the applications of diverse biomaterials, specifically natural nature-inspired synthetic materials in metal halide perovskite optoelectronics. Applications range from solar cells to light-emitting diodes, photodetectors, X-ray detectors. Emphasis is placed on intricate interactions between bio-additives crystals, highlighting their influence grain size, crystal orientation, boundaries, surface passivation. also explores advantages disadvantages each or material unique properties compared with conventional additives. Special attention given mechanistic functional viewpoints, showing how these biomaterials enhance device performance. Through additive engineering ecofriendly defects thin films can be effectively passivated, thus extending photostability some cases mechanical flexibility devices. provides valuable insights for selecting designing next-generation biomaterial additives, offering new prospects achieving high-performance layers advancing field peorvskite- based

Language: Английский

Optimizing Monolayers for High-Efficiency Methylammonium-Free Perovskite Solar Cells DOI

Zuwang Liu,

Bo Yu, Shengwei Shi

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: March 23, 2025

Self-assembled monolayers (SAMs) have been widely applied to perovskite solar cells (PSCs) due their transparency, tunability, selectivity, and diversity. While numerous studies focused on synthesizing various new types of SAMs enhance charge transport, there remains a need for further research reducing clusters improving the film coverage. Achieving uniform ensuring intimate contact with are processes that require deeper investigation. In this study, we employ additive engineering introduce micromolecule, 4-mercaptophenylacetic acid (4MA), into [4-(3,6-diphenyl-9H-carbazol-9-yl) butyl] phosphonic (Ph-4PACz). The incorporation 4MA can not only prevent aggregation Ph-4PACz through competitive mechanism, leading improved coverage uniformity, but also passivate layer reduce recombination in PSCs. As result, more homogeneous higher-quality films achieved both surface bottom layer. Moreover, optimizes alignment energy band enhances carrier transfer. These combined effects contribute high power conversion efficiency 23.8% methylammonium-free Our study demonstrates potential presents method producing SAMs, which is highly advantageous industrial applications.

Language: Английский

Citations

0
Substituent adjustment strategy on modifying perovskite/spiro-OMeTAD interface in perovskite solar cells DOI

Yufei Dong,

Cheng Peng,

Yufeng Li

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162140 - 162140

Published: March 1, 2025

Language: Английский

Citations

0
Open-air-processed Perfluoro(4-methylpent-2-ene)-modified MAPbI3 solar cells actualize 21.25% PCE and excellent humidity stability DOI
Huizhen Ke, Qinyi Zhang, Jun Zhan

et al.

Solar Energy, Journal Year: 2025, Volume and Issue: 294, P. 113508 - 113508

Published: April 16, 2025

Language: Английский

Citations

0
The prospects of biologically derived materials in perovskite solar cells DOI Creative Commons
Edwin T. Mombeshora, Edigar Muchuweni, Alexander Doolin

et al.

Applied Materials Today, Journal Year: 2024, Volume and Issue: 40, P. 102406 - 102406

Published: Aug. 31, 2024

Renewable materials should be appraised for advancing the sustainability of perovskite solar cells (PSCs). In particular, emerging applications biologically-derived (biomaterials) in PSCs have tremendous potential enhancing charge transport, device performance, flexibility, long-term stability, sustainability, and circularity strategies. This review discusses current status identifies new research directions biomaterials as either substitutes or composite constituents with other functional transport layers solvent systems PSCs. The understanding effect cellulose on power conversion efficiency (PCE), shape, stability is discussed terms surface roughness, wettability, optical properties, defect concentration, flexibility. Flexible that utilise are advantageous transportation widespread implementation, but suffer several possible adverse effects lower PCE due to decreased electron mobility from increased traps during bending cycles. Biomaterials considerable scope passivation, boosting PCE, when applied layers, particularly interfacial between layer active materials.

Language: Английский

Citations

2
Multifaceted Design of Surface Passivator for Upgraded Charge Extraction in Perovskite Solar Cells DOI

Mahdi Gassara,

Samrana Kazim, Shahzada Ahmad

et al.

Solar RRL, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 3, 2024

The nonradiative recombination arising from the interfaces of perovskite solar cells (PSCs) pose a hurdle, impacting both efficiency and stability devices. Functionalized organic molecules can passivate surface to suppress defects also fine‐tune microstructure. This in turn promotes reliability performance enhancement cells. Using design protocol, cyanoguanidine diiodide is synthesized employed as passivator for fabrication PSCs, boosted 20.44% 23.04% achieved. improvement stems an improved fill factor reaching up 80.64%, together with open‐circuit voltage ( V oc ) measuring 1119 mV. steady‐state photoluminescence microstructure passivated perovskites display significant modification film which favorably impacts charge carrier transfer at interface Spiro‐OMeTAD. Our findings suggest that cell due synergetic effect amino cyano functional groups along iodide reservoir passivator.

Language: Английский

Citations

2
Roles of Surfactants in Perovskite Solar Cells DOI Creative Commons

Abdullah Alasiri,

Khalid Zubair,

Shazzad Rassel

et al.

Heliyon, Journal Year: 2024, Volume and Issue: 10(20), P. e39141 - e39141

Published: Oct. 1, 2024

In photovoltaics, perovskite solar cells (PSCs) have shown efficiency improvement with scalable and low-cost fabrication. This work investigates the additions of surfactants to PSCs during after cell fabrication, how these enhance performance both hybrid PSCs. Various types were surveyed, including amphoteric, cationic, non-ionic, in addition other chemicals that are showing surfactant-like behavior. Surfactants found improve coverage area, reduce roughness, defects, oxygen, moisture pinholes. They also provided better control over film thickness, grain/spherulite size, crystal orientation. The mechanisms behind improvements explained, different studies literature categorized based on common themes.

Language: Английский

Citations

1
Natural and Nature‐Inspired Biomaterial Additives for Metal Halide Perovskite Optoelectronics DOI
Jiye Han, Ying Tian, Il Jeon

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 10, 2024

This comprehensive review meticulously categorizes and discusses the applications of diverse biomaterials, specifically natural nature-inspired synthetic materials in metal halide perovskite optoelectronics. Applications range from solar cells to light-emitting diodes, photodetectors, X-ray detectors. Emphasis is placed on intricate interactions between bio-additives crystals, highlighting their influence grain size, crystal orientation, boundaries, surface passivation. also explores advantages disadvantages each or material unique properties compared with conventional additives. Special attention given mechanistic functional viewpoints, showing how these biomaterials enhance device performance. Through additive engineering ecofriendly defects thin films can be effectively passivated, thus extending photostability some cases mechanical flexibility devices. provides valuable insights for selecting designing next-generation biomaterial additives, offering new prospects achieving high-performance layers advancing field peorvskite- based

Language: Английский

Citations

1