Hydrates of N-((10-Chloroanthracen-9-yl)methyl)-3-(1H-imidazol-1-yl)propan-1-ammonium Cobalt(II), Copper(II), and Zinc(II) 2,6-Pyridinedicarboxylate: Reversible Crystallization DOI Creative Commons
Abhay Pratap Singh, J.B. Baruah

ACS Omega, Journal Year: 2024, Volume and Issue: 9(48), P. 47848 - 47856

Published: Nov. 19, 2024

In a quest to explore interconvertible assemblies of hydrates cobalt(II), copper(II), and zinc(II) 2,6-pyridinedicarboxylate (26-pdc), complexes having cation chloro-substituted analogue N-{(10-chloroanthracen-9-yl)methyl}-3-(1H-imidazol-1-yl)propan-1-amine were investigated. the case cobalt copper complexes, crystallized stable hydrate less methanol guided by concentration-dependent crystallizations. The unit-cells crystals two each belong P1̅ space group but have different stoichiometries as well large differences in packing. These could be reversibly predictable manner. unit-cell volumes complex four-times smaller than that respective form (C2/c group), whereas similar had two-times volume form. cations forms assembled together formed zigzag ladder-like chains. spaces present between chains filled with clusters face stacked anions. transformation required bottom-up building process starting from hydrates. Fluorescence spectroscopic studies showed possibility zinc-complex solution, crystallization yielded only

Language: Английский

A Dual-Function Poly(vinyl alcohol) Hydrogel for Solar Water Production and Thermoelectric Energy Generation DOI Creative Commons
Yuhao Wang,

Ching‐Chieh Hsu,

Shao‐Huan Hong

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: March 4, 2025

This work addresses the dual challenges of seawater purification and converting low-grade waste heat into electricity, both which are crucial for sustainable resource management. It presents a combined approach that solves problems using self-fabricated device. The device generates temperature gradient through efficient photothermal conversion by placing thermoelectric hydrogels on top hydrogel. Poly(vinyl alcohol) (PVA) is used as matrix hydrogel was selected its biocompatibility ease processing. In order to enhance solar-driven water evaporation efficiency, ball-milled dititanium trioxide (Ti2O3) nanoparticles carbon nanotubes (CNTs) incorporated within PVA matrix. enables rate high 3.22 kg m–2 h–1. Additionally, also serves gels, soaked with K3[Fe(CN)6]/K4[Fe(CN)6] redox pair solution exploit thermogalvanic acid (TGC) effect. arrangement voltage generation reactions at hot cold ends. obtained excellent properties can be characterized ionic Seebeck coefficient (Si) 1.48 mV K–1 power density 9.6 mW after nine were connected in series. As result, this dual-functional simultaneously effectively purifies electricity. Outdoor testing shows daily production 9.2 stable 130 from hydrogels. advances energy technologies opens new avenues innovative applications renewable energy.

Language: Английский

Citations

0
Defect-rich MOF-303 as a dual acid-base heterogeneous catalyst for the one- pot Biginelli synthesis of dihydropyrimidinones DOI Creative Commons

Nuhaa Shaheed,

Ahmad Shaabani

Research Square (Research Square), Journal Year: 2025, Volume and Issue: unknown

Published: March 31, 2025

Abstract Bifunctional MOF-303 (Al) exhibits promising catalytic activity for the Biginelli reaction. However, its intrinsic microporosity may hinder reactant and product diffusion reducing efficiency. Introducing defects is crucial enhancing performance. In this work, defect-rich was prepared by grinding hydrothermally synthesized into a fine powder. The resulting material thoroughly characterized exhibited excellent performance in solvent-free synthesis of diverse dihydropyrimidinones under moderate reaction conditions, achieving yields between 94% over 99%. Moreover, catalyst successfully recycled five cycles with minimal loss. structures obtained products were confirmed IR, ¹H NMR, melting point analysis. simple preparation method using commercially inexpensive reagents, high mild recyclability highlight potential as an efficient sustainable

Language: Английский

Citations

0
Photothermal evaporator with low enthalpy of evaporation and hierarchical porous structure for efficient photothermal evaporation DOI

Cai‐Hua Liu,

Lei Xu,

Wang Zhenyu

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162282 - 162282

Published: April 1, 2025

Language: Английский

Citations

0
Three‐Phase Emulsion Derived Solar‐Thermal Reduced Graphene Oxide/Octadecane Phase‐Change Foam for Salt‐Resistant Day‐Night Water Evaporation DOI
Jing Wu, Peng Min,

Guang Yin

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 4, 2025

Abstract A solar‐thermal reduced graphene oxide/octadecane (RGO/oct) phase‐change foam is fabricated by the interfacial assembly of an air‐in‐oil‐in‐water three‐phase emulsion and subsequent chemical reduction oxide (GO) for day‐night evaporation desalination. The GO sheets assemble at water‐oct interfaces in presence amphiphilic alkyl glycoside while air pores are generated inside hydrophobic oct component under stirring, leading to GO/oct/air microspheres. During molding, chemically with ascorbic acid, resultant RGO/oct/air microspheres closed constitute RGO/oct foam. suppress heat conduction bulk water, prevents loss environment, hence enhancing localization capability exhibits a high rate 4.29 kg m −2 h −1 1‐sun irradiation. Interestingly, can release latent absence solar light irradiation, enabling water nighttime 2.30 . overlap molding allows rearrangement salt concentration gradients, exhibiting satisfactory resistance during stable brine 25 wt.% NaCl 10 h.

Language: Английский

Citations

0
One-pot synthesis of composite metal-organic framework for enhanced water adsorption: Feasibility and mechanism exploration DOI
Qiyang Wu, Xiang Ma, Libing Zheng

et al.

Desalination, Journal Year: 2024, Volume and Issue: unknown, P. 118251 - 118251

Published: Oct. 1, 2024

Language: Английский

Citations

0
Hydrates of N-((10-Chloroanthracen-9-yl)methyl)-3-(1H-imidazol-1-yl)propan-1-ammonium Cobalt(II), Copper(II), and Zinc(II) 2,6-Pyridinedicarboxylate: Reversible Crystallization DOI Creative Commons
Abhay Pratap Singh, J.B. Baruah

ACS Omega, Journal Year: 2024, Volume and Issue: 9(48), P. 47848 - 47856

Published: Nov. 19, 2024

In a quest to explore interconvertible assemblies of hydrates cobalt(II), copper(II), and zinc(II) 2,6-pyridinedicarboxylate (26-pdc), complexes having cation chloro-substituted analogue N-{(10-chloroanthracen-9-yl)methyl}-3-(1H-imidazol-1-yl)propan-1-amine were investigated. the case cobalt copper complexes, crystallized stable hydrate less methanol guided by concentration-dependent crystallizations. The unit-cells crystals two each belong P1̅ space group but have different stoichiometries as well large differences in packing. These could be reversibly predictable manner. unit-cell volumes complex four-times smaller than that respective form (C2/c group), whereas similar had two-times volume form. cations forms assembled together formed zigzag ladder-like chains. spaces present between chains filled with clusters face stacked anions. transformation required bottom-up building process starting from hydrates. Fluorescence spectroscopic studies showed possibility zinc-complex solution, crystallization yielded only

Language: Английский

Citations

0