Strong Electrochemiluminescence Response Derived from Ionic Chiral Covalent Organic Frameworks for Enantioselective Discrimination of Amino Acid Enantiomers via an Electrostatic Attraction Effect DOI

Shuyi Yuan,

Wenrong Cai, Lei Zhao

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(47), P. 65340 - 65347

Published: Nov. 13, 2024

Porous chiral materials accompanied by electrochemiluminescence (ECL) activity are rarely reported for enantioselective discrimination because of the big challenges to integrate stereogenic center and ECL-active unit in backbone. In present study, ionic covalent organic frameworks (iCCOFs) consisting pyridinium as species were prepared a facile strategy. We amazed that such iCCOFs could display strong cathodic ECL responses. Meanwhile, as-prepared performed quenching toward amino acid enantiomers, attributed enhanced photoinduced electron transfer process derived from formed complex between acids via an electrostatic attraction effect. The iCCOF with (S)-configuration was prone interact l-amino acids, producing lower intensity. maximum intensity ratio d- l-enantiomers 33.0. Finally, enantiomeric compositions measured presented good linear relation obtained intensity, which fit determination samples unknown purity. brief, results convince us this study advances new generation displays great potential sensing.

Language: Английский

Strategies for acquiring electrochemiluminescence spectra and their applications in mechanism studies and multi-analyte determination DOI
Lixin Zang, Haiyan Song, Huimin Zhao

et al.

TrAC Trends in Analytical Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 118259 - 118259

Published: April 1, 2025

Language: Английский

Citations

0
Strong Electrochemiluminescence Response Derived from Ionic Chiral Covalent Organic Frameworks for Enantioselective Discrimination of Amino Acid Enantiomers via an Electrostatic Attraction Effect DOI

Shuyi Yuan,

Wenrong Cai, Lei Zhao

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(47), P. 65340 - 65347

Published: Nov. 13, 2024

Porous chiral materials accompanied by electrochemiluminescence (ECL) activity are rarely reported for enantioselective discrimination because of the big challenges to integrate stereogenic center and ECL-active unit in backbone. In present study, ionic covalent organic frameworks (iCCOFs) consisting pyridinium as species were prepared a facile strategy. We amazed that such iCCOFs could display strong cathodic ECL responses. Meanwhile, as-prepared performed quenching toward amino acid enantiomers, attributed enhanced photoinduced electron transfer process derived from formed complex between acids via an electrostatic attraction effect. The iCCOF with (S)-configuration was prone interact l-amino acids, producing lower intensity. maximum intensity ratio d- l-enantiomers 33.0. Finally, enantiomeric compositions measured presented good linear relation obtained intensity, which fit determination samples unknown purity. brief, results convince us this study advances new generation displays great potential sensing.

Language: Английский

Citations

1