Materials Science in Semiconductor Processing, Journal Year: 2024, Volume and Issue: 188, P. 109249 - 109249
Published: Dec. 29, 2024
Language: Английский
Materials Science in Semiconductor Processing, Journal Year: 2024, Volume and Issue: 188, P. 109249 - 109249
Published: Dec. 29, 2024
Language: Английский
Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162933 - 162933
Published: March 1, 2025
Language: Английский
Citations
2Published: Jan. 1, 2025
Abstract: Element doping is critical in regulating the electronic structure to enhance N2 adsorption, opening up new possibilities for achieving highly efficient photocatalytic nitrogen reduction reactions (pNRR). In this study, we successfully prepared Cu-doped BiOBr (Cu-BiOBr) operating a simple solvothermal method. Density Functional Theory (DFT) calculations and experimental investigations were employed explore how Cu influences performance of pNRR over BiOBr. The DFT analysis indicates that alters structure, lowers energy barrier reaction, narrows bandgap. This adjustment leads remarkable NH3 production rate 466.3 μmol⋅gcat−1⋅h−1 without need sacrificial agents 2% Cu-BiOBr sample. addition, based on findings in-situ FTIR, detailed mechanism adsorption/activation hydrogenation reaction N ≡ bonds was proposed. research introduces prospective way designing transition metal-doped catalysts with regulated structures pNNR, which has significant implications advancing other material systems.
Language: Английский
Citations
0Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: unknown, P. 105807 - 105807
Published: Jan. 1, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132501 - 132501
Published: March 1, 2025
Language: Английский
Citations
0ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 6334 - 6345
Published: April 4, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 133120 - 133120
Published: April 1, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 133428 - 133428
Published: May 1, 2025
Language: Английский
Citations
0Materials Science in Semiconductor Processing, Journal Year: 2024, Volume and Issue: 188, P. 109249 - 109249
Published: Dec. 29, 2024
Language: Английский
Citations
0