Spray Drying Synthesis of Stable Cu Catalyst Supported on Carbon with High C2 Product Selectivity in Co2 Electrolysis

Published: Jan. 1, 2025

Language: Английский

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Photocatalyzed Aerobic Oxidation of Thiols to Disulfides Using Cu₂O Polyhedra

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: March 13, 2025

To further demonstrate semiconductor facet effect to photocatalytic organic transformations and address a lack of using simple polyhedral particles for disulfide bond formation, Cu2O cubes, octahedra, rhombic dodecahedra were used photocatalyze aerobic oxidation 4-methylbenzenethiol. After reaction condition optimization, crystals N,N,N′,N′-tetramethylethylenediamine (TMEDA) added 4-methylbenzenethiol in ethanol thiol 1,2-di-p-tolyldisulfane under 390 nm light-emitting diode (LED) lamp irradiation just 5 min. Rhombic gave the highest product yield, followed by commercial powder. subsequently employed thiols bearing diverse scope substituents with satisfactory yields. Reactive species trapping experiments performed support plausible mechanism. Semiconductor surface control can be but highly effective strategy enhancing transformations.

Language: Английский

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Regulation of Cu-MOF reconstruction for enhanced CO2 electroreduction

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125412 - 125412

Published: April 1, 2025

Language: Английский

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Spray drying synthesis of stable Cu catalyst supported on carbon with high C2 product selectivity in CO2 electrolysis

Molecular Catalysis, Journal Year: 2025, Volume and Issue: 582, P. 115162 - 115162

Published: May 3, 2025

Language: Английский

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Mesoporous Cu2O microspheres for highly efficient C2 chemicals production from CO2 electroreduction

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 671, P. 496 - 504

Published: May 23, 2024

Language: Английский

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