Food Chemistry X,
Journal Year:
2024,
Volume and Issue:
25, P. 102093 - 102093
Published: Dec. 12, 2024
Total
antioxidant
capacity
(TAC)
is
an
important
indicator
for
assessing
the
merit
of
natural
plants
and
foods.
Herein,
a
visual
TAC
assay
developed
based
on
oxidase-like
activity
nitrogen-doped
carbon
nanotubes
loaded
with
Fe
nanoparticles
(FeNPs@NCNT),
which
prepared
via
high-temperature
pyrolysis
metal-organic
framework
precursors
can
catalyze
oxidation
colorless
Advanced Healthcare Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: July 17, 2024
Nanozymes,
with
their
versatile
composition
and
structural
adaptability,
present
distinct
advantages
over
natural
enzymes
including
heightened
stability,
customizable
catalytic
activity,
cost-effectiveness,
simplified
synthesis
process,
making
them
as
promising
alternatives
in
various
applications.
Recent
advancements
nanozyme
research
have
shifted
focus
from
serendipitous
discovery
toward
a
more
systematic
approach,
leveraging
machine
learning,
theoretical
calculations,
mechanistic
explorations
to
engineer
nanomaterial
structures
tailored
functions.
Despite
its
pivotal
role,
electron
transfer,
fundamental
process
catalysis,
has
often
been
overlooked
previous
reviews.
This
review
comprehensively
summarizes
recent
strategies
for
modulating
transfer
processes
fine-tune
the
activity
specificity
of
nanozymes,
electron-hole
separation
carrier
transfer.
Furthermore,
bioapplications
these
engineered
antimicrobial
treatments,
cancer
therapy,
biosensing
are
also
introduced.
Ultimately,
this
aims
offer
invaluable
insights
design
nanozymes
enhanced
performance,
thereby
advancing
field
research.
Analytical Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 25, 2025
Here,
we
report
a
"off-on
model"-based
colorimetric
sensor
without
the
assistance
of
H2O2,
achieved
by
organic
solvent-processed
amorphous
BiVO4
nanoparticles
favorable
for
large-scale
manufacturing.
The
material
beyond
traditional
crystalline
nanozymes
has
both
vanadium
vacancy
(Vv)
and
oxygen
(Ov),
as
well
single
oxidase-like
activity
with
hydroxyl
radical
(•OH)
superoxide
anion
(O2•-)
electron
acceptors.
Despite
high
enzymatic
performance,
dual-defect-rich
preserves
good
long-term
in
either
buffer
solution
or
solid
state.
specially
designed
is
capable
accelerating
TMB
oxidation
presence
polyphenols,
thus
leading
to
an
interesting
signal-intensified
response.
This
probably
due
coordination
ortho
dihydroxyl
group
polyphenols
catalyst
replacing
surface-adsorbed
NO3-,
which
results
faster
charge
transfer
between
substrate
and,
thus,
more
rapid
depletion
radicals
oxidation.
Based
on
these
findings,
platform
proanthocyanidin
(PAC)
B2
established
limit
detection
(LOD)
low
65
nM
specificity.
shows
higher
sensitivity
than
standard
Porter
method
(LOD:
0.29
μM)
comparable
accuracy
when
analyzing
PAC
commercially
available
grape
seed
capsules,
quantitative
recoveries
varying
from
104.0
108.3%
relative
deviations
ranging
1.7
5.7%.
To
date,
this
only
nanozyme-based
chemical
that
active
signal
model"
reducing
polyphenols.
Also,
seems
quite
general,
it
can
be
used
sensing
series
specific
addition
B2.
ACS Sensors,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 4, 2024
High
sensitivity,
low
concentration,
and
excellent
selectivity
are
pronounced
primary
challenges
for
semiconductor
gas
sensors
to
monitor
acetone
from
exhaled
breath.
In
this
study,
nitrogen-doped
carbon
quantum
dots
(N-CQDs)
with
high
reactivity
were
used
activate
dandelion-like
hierarchical
tungsten
oxide
(WO