Applied Clay Science, Journal Year: 2024, Volume and Issue: 261, P. 107578 - 107578
Published: Sept. 20, 2024
Language: Английский
Applied Clay Science, Journal Year: 2024, Volume and Issue: 261, P. 107578 - 107578
Published: Sept. 20, 2024
Language: Английский
Journal of Molecular Liquids, Journal Year: 2025, Volume and Issue: unknown, P. 127116 - 127116
Published: Feb. 1, 2025
Language: Английский
Citations
2Heliyon, Journal Year: 2025, Volume and Issue: 11(3), P. e42396 - e42396
Published: Feb. 1, 2025
Highlights•First-time synthesis of CoZr-LDH and its composite with graphene oxide (GO) using a green, solventless mechanochemical method alongside hydrothermal synthesis.•Novel adsorption study metronidazole, critical environmental antibiotic pollutant, revealing detailed interactions within the CoZr-LDH/GO structure.•Comprehensive evaluation capacity, demonstrating structural benefits pollutant interaction mechanisms for first time.•Innovative comparison quantum calculations Monte Carlo locator simulations, applied time to predict analyze on LDH LDH/GO surfaces, providing significant insights into efficiency.AbstractCoZr-LDH Graphene Oxide nanocomposite were synthesized by methods, respectively, absorb metronidazole as from an aqueous solution. In this study, Tetravalent divalent metal cations employed. The characterized SEM, EDS, IR, BET, XRD analyses. process both adsorbents, parameters such initial solution pH, adsorbent dose, drug concentration, contact optimized obtain maximum capacity. performance was thoroughly investigated removal (MNZ), contaminant. demonstrated optimal adsorption, yielding experimental qe value 189.1376 mg g-1. Conversely, exhibited superior under optimum conditions, achieving remarkable 906.5688 g-1.The isotherms, including Langmuir, Freundlich, Redlich-Peterson models, fitted data describe surface characteristics. Additionally, kinetic studies involving pseudo-first-order pseudo-second-order models performed, process. Post-adsorption characterization confirmed successful between MNZ adsorbents. This emphasizes potential GO-enhanced effective addressing status in wastewater.To comprehensively CoZr-LDH/GO, theoretical analyses conducted computational method. approach, known simulating numerous particle trajectories statistical averaging, allowed in-depth examination various conditions. findings, validated against data, enhanced model accuracy provided deeper behaviors complex environments.Graphical abstract
Language: Английский
Citations
1Process Safety and Environmental Protection, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 1, 2024
Language: Английский
Citations
7Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142333 - 142333
Published: April 1, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 133008 - 133008
Published: April 1, 2025
Language: Английский
Citations
0Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140283 - 140283
Published: Oct. 1, 2024
Language: Английский
Citations
2Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(5), P. 113878 - 113878
Published: Aug. 23, 2024
Language: Английский
Citations
1Research on Chemical Intermediates, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 18, 2024
Language: Английский
Citations
1C – Journal of Carbon Research, Journal Year: 2024, Volume and Issue: 10(3), P. 75 - 75
Published: Aug. 20, 2024
Hydrothermal carbonation carbon (HTCC) is emerging as a promising material for the adsorption and photodegradation of environmental contaminants. However, chemical structural properties HTCC derived from different lignocellulose biomass have obvious impacts on photodegradation. This work employed three components, including cellulose, hemicellulose, lignin to synthesize within hydrothermal temperature range 210~290 °C. In comparison cellulose (HTCC-L) demonstrated optimal synergistic ability TC degradation, achieving 63.5% removal efficiency 120 min. Characterization highlighted crucial involvement oxygenated functional groups, especially carboxyl presented surface HTCC-L in adsorption. Moreover, was found follow non-radical mechanism, characterized by charge transformation occurring between excited unpaired electrons adsorbed its surface. clarified differences components organic pollutants, provided novel perspective application water treatment.
Language: Английский
Citations
0Magnetochemistry, Journal Year: 2024, Volume and Issue: 10(9), P. 64 - 64
Published: Aug. 31, 2024
In this paper, MIL-88D (Fe) with spindle shape was prepared by the hydrothermal synthesis method, a metal oxide new structure obtained calcination at different temperatures as precursor, and magnetic iron composite successfully. At same time, it used an adsorption material for of heavy ions Cu2+. The influence initial pH value time on effect investigated, kinetics isotherm were further fitted, mechanism preliminarily analyzed. results show that composites have good capacity is important parameter affects effect. Cu2+ reached equilibrium in 30 min. conforms to second-order reaction Langmuir equation, which indicates process mainly occurs through chemisorption typical single-molecular-layer adsorption.
Language: Английский
Citations
0