Electrocatalytic Ammonia Production from Nitrogen with Enhanced Faradaic Efficiency Using Nanostructured Bi2MoO6 DOI

Sthitapragyan Patnaik,

Debabrata Pradhan

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(42), P. 15551 - 15561

Published: Oct. 8, 2024

Electrochemical nitrogen reduction reaction (ENRR) under ambient conditions is anticipated as a viable green substitute to the commercial Haber–Bosch process. However, ENRR severely limited by slow production rate of ammonia, which highly dependent on electrocatalysts used. An efficient electrocatalyst for crucial greener ammonia production. Herein, solvothermal method demonstrated synthesize Bi2MoO6 nanostructures using 2-propanol and ethylene glycol solvents varying volume ratios. The results show that solvent has significant impact morphologies other parameters, including surface area, charge transfer phenomena, electrocatalytic properties, determine optimized catalyst fantastic faradaic efficiency 19.0% an NH3 yield 24.9 μg h–1 mgcat.–1 at −0.6 V vs reversible hydrogen electrode are much higher than those any independent been previously reported. Moreover, synthesized exhibits exceptional durability confirmed through chronoamperometry recycling tests.

Language: Английский

Innovative multi-Z-scheme Bi2MoO6/BiOBr0.75/BiOI0.25/g-C3N4 quaternary composite with superior visible-light photocatalytic performance for degrading rhodamine B and furfural DOI
Hayet Lallali, Abdelhadi Bentouami,

Mohamed Cherief

et al.

Sustainable materials and technologies, Journal Year: 2025, Volume and Issue: unknown, P. e01391 - e01391

Published: April 1, 2025

Language: Английский

Citations

0
Construction and properties of highly efficient Ag6Si2O7/C-WO3 visible light photocatalyst for water purification DOI
Fangxiao Wang,

Shana Xia,

Xinru Qin

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: 705, P. 135700 - 135700

Published: Nov. 4, 2024

Language: Английский

Citations

2
Electrocatalytic Ammonia Production from Nitrogen with Enhanced Faradaic Efficiency Using Nanostructured Bi2MoO6 DOI

Sthitapragyan Patnaik,

Debabrata Pradhan

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(42), P. 15551 - 15561

Published: Oct. 8, 2024

Electrochemical nitrogen reduction reaction (ENRR) under ambient conditions is anticipated as a viable green substitute to the commercial Haber–Bosch process. However, ENRR severely limited by slow production rate of ammonia, which highly dependent on electrocatalysts used. An efficient electrocatalyst for crucial greener ammonia production. Herein, solvothermal method demonstrated synthesize Bi2MoO6 nanostructures using 2-propanol and ethylene glycol solvents varying volume ratios. The results show that solvent has significant impact morphologies other parameters, including surface area, charge transfer phenomena, electrocatalytic properties, determine optimized catalyst fantastic faradaic efficiency 19.0% an NH3 yield 24.9 μg h–1 mgcat.–1 at −0.6 V vs reversible hydrogen electrode are much higher than those any independent been previously reported. Moreover, synthesized exhibits exceptional durability confirmed through chronoamperometry recycling tests.

Language: Английский

Citations

1