Achiral and chiral metal-organic frameworks (MOFs) as an efficient catalyst for organic synthesis

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 533, P. 216536 - 216536

Published: Feb. 26, 2025

Language: Английский

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Enantioselective Recognition Driven Photocatalytic Degradation of d-Tryptophan Enantiomers Based on l-Cysteine-Modified β-Cyclodextrin

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 26, 2025

The enantioselective recognition and separation of racemic tryptophan are significant importance in the fields medicine, pharmaceutics, biochemistry. However, conventional methods costly, energy intensive, environmentally unfriendly. In this case, l-Cys with amino (-NH2) sulfhydryl (-SH) groups was chosen to modify β-CD a chiral cavity achieve self-assembly via hydrogen bonding, which not only serves as an electrochemical sensor enhanced sites at sensing interface but also achieves higher enantioselectivity for d-tryptophan enantiomers through bonding between host guest. Moreover, were subsequently degraded under catalytic conditions simulating visible light, new approach introduce properties photocatalysis without organic synthesis. use inclusion-complex formation combined simple technology photocatalytic degradation techniques efficiently rapidly identify degrade harmful d-type acid offers avenues, would have great potential future studies.

Language: Английский

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Bioinspired bi-amino acid Ce-MOFs Boosting oxidase-like Activity: Dual-mode Aflatoxin Detection, antimicrobial activity platform

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161977 - 161977

Published: March 1, 2025

Language: Английский

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Chitosan-wrapped MOF-808 surface for amplifying electrochemical chiral recognition signal

Microchimica Acta, Journal Year: 2025, Volume and Issue: 192(6)

Published: May 19, 2025

Language: Английский

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