Advances in Self-Healable and 3D Printable Biobased Elastomers

Polymer, Journal Year: 2025, Volume and Issue: unknown, P. 128020 - 128020

Published: Jan. 1, 2025

Language: Английский

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Recent Advances in Healable Carbon-Fiber-Reinforced Epoxy Resin Composite Laminate: Preparation and Properties

ACS Applied Polymer Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 10, 2025

Language: Английский

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Self-healing and recyclable polyurethane-based solid-state polymer electrolyte via Diels-Alder dynamic network

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1321, P. 139793 - 139793

Published: Aug. 25, 2024

Language: Английский

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Synergistic Inherent and Dynamic Cross-Links for Self-Healable Polydimethylsiloxane Elastomer Foams

ACS Applied Polymer Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 16, 2025

The preparation of foams with self-healing properties and stable cell structures continues to present significant challenges. In this study, a polydimethylsiloxane elastomer featuring dual network structure was developed. A dynamic cross-linking network, formed by hydrogen disulfide bonds, imparted capabilities the elastomer. inclusion agent created an inherent that improved mechanical melt strength synthesized demonstrated exceptional performance, achieving efficiency 92.89%, along impressive properties, including tensile 6.32 MPa elongation at break 1277.80%. Additionally, foam fabricated using supercritical carbon dioxide (sc-CO2) foaming method. With increase in cross-linking, size decreased from 11.88 8.60 μm, while density increased 2.04 × 109 2.71 cells/cm3, resulting uniform distribution within foam. Microcracks were effectively healed 10 min 80 °C, morphology remained after 96 h exposure environmental conditions. This dual-network exhibited excellent performance structure.

Language: Английский

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Types of Crosslinkers and Their Applications in Biomaterials and Biomembranes

Chemistry, Journal Year: 2025, Volume and Issue: 7(2), P. 61 - 61

Published: April 11, 2025

Biomaterials and biomembranes play a crucial role in variety of applications, particularly the medical field due to their ability mimic natural biological structures functions. Crosslinkers also an important enhancing structural integrity functionality biomaterials design biomembranes. This review article explores fundamentals biomembranes, with particular focus on crosslinkers biology, chemistry medicine. We explore various types commonly used synthesis, examining chemical structure, classification, synthesis methods. Additionally, we analyze properties interactions, highlighting impact, cellular behavior cytotoxicity. further emphasizes recent advances innovation, tissue engineering, drug delivery, wound healing. Finally, conclude by addressing current challenges suggesting potential futures directions for research this field.

Language: Английский

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Recent progress in intrinsic self-healing polymer materials: Mechanisms, challenges and potential applications in oil and gas development

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161906 - 161906

Published: March 1, 2025

Language: Английский

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Self-healing bismaleimide resin via “click” reactions: impact of structure on healing efficiency

Journal of Polymer Research, Journal Year: 2024, Volume and Issue: 31(12)

Published: Dec. 1, 2024

Language: Английский

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A bio-based, biodegradable, self-healable, and recyclable dynamic crosslinking network for sustainable high-performance electromagnetic interference shielding

Materials Today Chemistry, Journal Year: 2024, Volume and Issue: 43, P. 102473 - 102473

Published: Dec. 20, 2024

Language: Английский

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Diels–Alder Cycloaddition of 2,5-Bis(hydroxymethyl)furan (BHMF) and N-Phenylmaleimide Derivatives

ACS Omega, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 14, 2024

Currently, amidst atmospheric menace where natural calamities such as wildfire and floods are becoming more frequent than ever, biobased derivatives offer a sustainable alternative to conventional ways, for instance, petrochemical commodities. Biobased products, obtained from agricultural waste, including 5-(hydroxymethyl)furfural (HMF), 2,5-bis(hydroxymethyl)furan (BHMF), 2,5-furandicarboxylic acid (FDCA) promising chemical platforms in the biorefinery, which is yet be explored. The Diels–Alder cycloaddition of BHMF N-phenylmaleimide under optimal reaction conditions investigated this report. First, HMF reduced presence NaBH4, then produce adducts. All novel compounds synthesized acceptable yields effectively characterized by employing important techniques one-dimensional (1D) NMR spectroscopy (1H, 13C, DEPT-90, DEPT- 135), two-dimensional (2D) (1H–1H COSY, 1H–13C HSQC, HMBC), IR spectroscopy, elemental analysis, mass spectrum (QTOF), single-crystal X-ray diffraction (SC-XRD). Furthermore, study underlines necessity synthetic methodologies gives critical insights into progress ecologically friendly methodologies, providing new avenue tunable precursor challenging functionalized polymer future.

Language: Английский

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Surprisingly fast self-healing coatings with anti-fog and antimicrobial activities via host-guest interaction

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 680, P. 139 - 150

Published: Nov. 1, 2024

Language: Английский

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