Micropores in Hollow Organic Cage Nanocapsule as a Size Exclusion Gate: Cage Entrapped Pd(II)-Catalyst for Efficient Cross-Coupling Reaction DOI
Rupa Bargakshatriya, Rabindranath Lo, Amitava Das

et al.

Langmuir, Journal Year: 2024, Volume and Issue: 40(17), P. 8820 - 8826

Published: April 15, 2024

Hollow porous organic capsules (HPOCs) with an entrapped active catalyst have nanosized cavities, providing the benefits of a nanoreactor, as well separation catalysts from reaction medium via pores acting size-exclusion gate. Such purpose-built HPOCs desired molecular weight cutoffs offer advantages semipermeable membrane and sustainable chemical process that excludes energy-extensive separation. Here, we report newly synthesized HPOC Pd(PPh3)2Cl2 for demonstrating Suzuki–Miyaura coupling proof concept.

Language: Английский

Micropores in Hollow Organic Cage Nanocapsule as a Size Exclusion Gate: Cage Entrapped Pd(II)-Catalyst for Efficient Cross-Coupling Reaction DOI
Rupa Bargakshatriya, Rabindranath Lo, Amitava Das

et al.

Langmuir, Journal Year: 2024, Volume and Issue: 40(17), P. 8820 - 8826

Published: April 15, 2024

Hollow porous organic capsules (HPOCs) with an entrapped active catalyst have nanosized cavities, providing the benefits of a nanoreactor, as well separation catalysts from reaction medium via pores acting size-exclusion gate. Such purpose-built HPOCs desired molecular weight cutoffs offer advantages semipermeable membrane and sustainable chemical process that excludes energy-extensive separation. Here, we report newly synthesized HPOC Pd(PPh3)2Cl2 for demonstrating Suzuki–Miyaura coupling proof concept.

Language: Английский

Citations

1