Rational Design of Catalysts with Spinel Nanostructures for Thermal-Driven C1 Conversion DOI
Xiaoxue Han, Dan Guo, Yong Wang

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(13), P. 9812 - 9828

Published: June 17, 2024

The oriented conversion of C1 molecules including CO, CO2, CH4, and CH3OH has received great attention in the past few decades because its essential role sustainable chemistry. Spinel oxides with fine hardness, thermal stability, tunable chemical properties are advantageous catalysts or precursors activation inert for production high-value-added chemicals. This review provides a thorough overview recent developments spinel-structured nanocatalysts processes thermal-driven conversion, highlighting advantages deriving active metals, stabilizing metal cations, constructing adjacent synergic sites, tuning oxygen vacancies. Finally, potential challenges development directions discussed application reactions.

Language: Английский

Understanding kinetically interplaying reverse water-gas shift and Fischer-Tropsch synthesis during CO2 hydrogenation over Fe-based catalysts DOI
Minjie Xu, Chenxi Cao, Jing Xu

et al.

Applied Catalysis A General, Journal Year: 2022, Volume and Issue: 641, P. 118682 - 118682

Published: May 26, 2022

Language: Английский

Citations

25
Introducing a novel catalyst for efficient conversion of CO2 into syngas through reverse-water-gas-shift (RWGS) reactions based on highly mesoporous structures MCM-41: Influence of the Fe incorporation DOI
Mohammad Reza Kiani, Ramtin Kamandi,

Kimia Nozarian

et al.

Energy Conversion and Management, Journal Year: 2024, Volume and Issue: 304, P. 118247 - 118247

Published: Feb. 28, 2024

Language: Английский

Citations

5
Structure and Activity Comparison of Cu/CeyZr1–yOx Series Catalysts in the Reverse Water–Gas Shift Reaction DOI
Nuo Xu, Jie Ren,

Hao Lou

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: 38(8), P. 7158 - 7166

Published: April 2, 2024

Cu-based catalysts with abundant oxygen vacancies have attracted great attention for the reverse water–gas shift (RWGS) reaction because of their enhanced activity CO2 adsorption and activation. However, effect vacancy origin on mechanism RWGS are still unclear. Herein, various Cu/CeyZr1–yOx different Ce/Zr ratios were designed used RWGS, results showed that Cu/Ce0.9Zr0.1Ox catalyst exhibited highest conversion (57.5%) 100% CO selectivity. The characterization possessed highly dispersed Cu, vacancies, optimized basic sites, synergistic three factors led to stability. Both formate carbonate pathways been confirmed Cu/CeyZr1–yOx, while dominant path is between Cu/ZrO2 Cu/CeO2.

Language: Английский

Citations

5
Active pairs of Cu0/Cu+ for CO2 hydrogenation DOI
Wei Zhou, Mazhar Ahmed Memon,

Mengmeng Niu

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: unknown

Published: May 1, 2024

Language: Английский

Citations

5
Rational Design of Catalysts with Spinel Nanostructures for Thermal-Driven C1 Conversion DOI
Xiaoxue Han, Dan Guo, Yong Wang

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(13), P. 9812 - 9828

Published: June 17, 2024

The oriented conversion of C1 molecules including CO, CO2, CH4, and CH3OH has received great attention in the past few decades because its essential role sustainable chemistry. Spinel oxides with fine hardness, thermal stability, tunable chemical properties are advantageous catalysts or precursors activation inert for production high-value-added chemicals. This review provides a thorough overview recent developments spinel-structured nanocatalysts processes thermal-driven conversion, highlighting advantages deriving active metals, stabilizing metal cations, constructing adjacent synergic sites, tuning oxygen vacancies. Finally, potential challenges development directions discussed application reactions.

Language: Английский

Citations

5