DFT studies on rhodium(iii)-catalyzed synthesis of indanones from N-methoxybenzamides via C–H activation reaction DOI
Qianqian Li, Meiju Wei

New Journal of Chemistry, Journal Year: 2022, Volume and Issue: 46(34), P. 16576 - 16583

Published: Jan. 1, 2022

Rh( iii )-catalyzed reaction of N -methoxybenzamides with β-trifluoromethyl-α,β-unsaturated ketones to produce different products under conditions.

Language: Английский

Rh-Catalyzed Functionalization of N-Heterocycles Through C–H Activation DOI
Sanjeev Kumar, Vinaykumar Kanchupalli

Topics in heterocyclic chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 89 - 157

Published: Jan. 1, 2024

Language: Английский

Citations

0
Rhodium-catalyzed cascade C–H activation/annulation/1,6-acyl migration: direct construction of free N–H indoles under mild conditions DOI
Raju S. Thombal, Mohammad Aslam, Sonaimuthu Mohandoss

et al.

New Journal of Chemistry, Journal Year: 2022, Volume and Issue: 46(13), P. 6126 - 6133

Published: Jan. 1, 2022

Rh-Catalyzed regioselective cascade C–H activation/annulation/1,6-acyl migration of N -acetanilides with alkynes via C–C/C–N/C–O bond formation is developed.

Language: Английский

Citations

2
Mechanistic Insights Into the Rhodium-Catalyzed C–H Alkenylation/Directing Group Migration and [3+2] Annulation: A DFT Study DOI
Baoping Ling,

Wang Shuangjie,

Yuxin Xie

et al.

The Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 88(7), P. 4494 - 4503

Published: March 27, 2023

The mechanism of the rhodium-catalyzed C-H alkenylation/directing group migration and [3+2] annulation N-aminocarbonylindoles with 1,3-diynes has been investigated DFT calculations. On basis mechanistic studies, we mainly focus on regioselectivity 1,3-diyne inserting into Rh-C bond N-aminocarbonyl directing involved in reactions. Our theoretical study uncovers that undergoes a stepwise β-N elimination isocyanate reinsertion process. As studied this work, finding is also applicable to other relevant Additionally, role Na+ versus Cs+ cyclization reaction probed.

Language: Английский

Citations

0
Cobalt-catalyzed domino process for the synthesis of 2-aminoquinolines DOI
Jing Wang, Yiwen Zhu, Jun Ying

et al.

Tetrahedron, Journal Year: 2023, Volume and Issue: 146, P. 133631 - 133631

Published: Sept. 2, 2023

Language: Английский

Citations

0
DFT studies on rhodium(iii)-catalyzed synthesis of indanones from N-methoxybenzamides via C–H activation reaction DOI
Qianqian Li, Meiju Wei

New Journal of Chemistry, Journal Year: 2022, Volume and Issue: 46(34), P. 16576 - 16583

Published: Jan. 1, 2022

Rh( iii )-catalyzed reaction of N -methoxybenzamides with β-trifluoromethyl-α,β-unsaturated ketones to produce different products under conditions.

Language: Английский

Citations

0