Modulating photogenerated electron density of Pr single-atom sites by coordination environment engineering for boosting photoreduction of CO2 to CH3OH DOI
Minzhi Ma, Zeai Huang, Lina Li

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 330, P. 122626 - 122626

Published: March 14, 2023

Language: Английский

The photocatalytic H2O2 production: Design strategies, Photocatalyst advancements, environmental applications and future prospects DOI
Asif Hayat, Zeeshan Ajmal, Abdullah Yahya Abdullah Alzahrani

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 522, P. 216218 - 216218

Published: Sept. 21, 2024

Language: Английский

Citations

17
Dual-cocatalysts-embedded hollow photocatalysis system drives solar fuel production DOI

Tianwei Zhao,

Jinyan Xiong,

Wei Li

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160313 - 160313

Published: Feb. 1, 2025

Language: Английский

Citations

2
Entropy-Increasing Single-Atom Photocatalysts Strengthening the Polarization Field for Boosting H2O Overall Splitting into H2 DOI

Jiaqi Huang,

Shan Yang, Shujuan Jiang

et al.

ACS Catalysis, Journal Year: 2022, Volume and Issue: 12(23), P. 14708 - 14716

Published: Nov. 16, 2022

Entropy-increasing single-atom photocatalytic systems with a strengthened polarization field have been constructed by confining Ni atoms within interlayers of g-C3N4 nanotubes (Ni-C3N4Ts) directly using the hydrothermal method for H2O overall splitting into H2 fuel. Theoretical and experimental results indicate that confinement increases entropy system, which induces field, resulting in smooth transfer photogenerated e– h+ from Ni-C3N4T to surface Ni-(s-triazine)4 active sites via Ni–N bonds as channels. Stable stoichiometric O2 evolution rates an optimal solar-to-H2 efficiency 1.23% obtained under AM 1.5 G solar simulator irradiation. Mechanistic studies based on density functional theory (DFT) calculations situ DRIFTS measurement confirm abundant entropy-increasing system play key role translation, rotation, transformation protons intermediates reduction oxidation.

Language: Английский

Citations

45
Review on the Application of Semiconductor Heterostructures in Photocatalytic Hydrogen Evolution: State-of-the-Art and Outlook DOI
Shanshan Wang,

Wanyi Liao,

Hong Su

et al.

Energy & Fuels, Journal Year: 2023, Volume and Issue: 37(3), P. 1633 - 1656

Published: Jan. 24, 2023

Semiconductor materials, as the core of a system for collecting solar energy, possess excellent carrier separation efficiency and photochemical stability in photocatalytic process. Single semiconductor materials photocatalysts suffer from disadvantages such low visible light absorption performance quick photoelectron recombination rate. The can be significantly improved by constructing heterogeneous structures. In this review, practical application heterostructure developed recent years hydrogen evolution photocatalysis is described. Five kinds heterostructures commonly used field are highlighted. Since construction nanomaterial enhances activity, we describe detail fundamental understanding capabilities principles different photocatalysts. particular, effect formation on ability terms enhanced accelerated charge transfer discussed. Finally, challenges prospects introduced. This review provides reference study heterostructures.

Language: Английский

Citations

40
Modulating photogenerated electron density of Pr single-atom sites by coordination environment engineering for boosting photoreduction of CO2 to CH3OH DOI
Minzhi Ma, Zeai Huang, Lina Li

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 330, P. 122626 - 122626

Published: March 14, 2023

Language: Английский

Citations

40