Promoting n-Butane Dehydrogenation over PtMn/SiO2 through Structural Evolution Induced by a Reverse Water-Gas Shift Reaction DOI
Yi Liu, Guanghui Zhang, Shida Liu

et al.

ACS Catalysis, Journal Year: 2022, Volume and Issue: 12(21), P. 13506 - 13512

Published: Oct. 20, 2022

Structural evolution of heterogeneous catalysts often occurs during catalytic reactions. In this contribution, the structural a PtMn/SiO2 catalyst reverse water-gas shift (RWGS) reaction was investigated using detailed spectroscopic characterizations. The results show that Mn atoms on PtMn nanoparticle surface were partially removed RWGS reaction, which increases ratio Pt sites with lower coordination number surface, leading to 10-fold increase rate in n-C4H10 dehydrogenation from 1.85 21.93 mol gPt–1 h–1 and decrease apparent activation energy 50 33 kJ mol–1. This work provides dimension improving performance alkane over Pt-based bimetallic through CO2 hydrogenation.

Language: Английский

Modulation of acidic–basic and metal–carrier interactions in CO2-assisted propane dehydrogenation over Ga2Lax/ZSM-5 catalysts DOI

Xinhua Peng,

Xiaohua Cao, Huaiyu Xu

et al.

New Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

La effectively promotes propylene production over Ga/ZSM-5 catalyst in CO 2 -ODHP.

Language: Английский

Citations

0
Comparative study on transition metal promoted Pt/SiO2 for oxidative dehydrogenation of propane with carbon dioxide DOI Creative Commons
Hengbo Zhang, Guoqing Yang, Jiageng Li

et al.

Journal of CO2 Utilization, Journal Year: 2025, Volume and Issue: 97, P. 103116 - 103116

Published: May 17, 2025

Language: Английский

Citations

0
High transformation of propane in reaction with CO2 to propylene on ZrO2-combined Fe-based catalysts DOI
Yuan Wang, Yan Chen, Jianli Zhang

et al.

Catalysis Science & Technology, Journal Year: 2023, Volume and Issue: 13(19), P. 5734 - 5744

Published: Jan. 1, 2023

Combined Fe 2 O 3 – n ZrO with preservation of active 4 and tunable acid–base properties for high conversion C H 8 (CO ) to 6 .

Language: Английский

Citations

9
CO2-assisted oxidation dehydrogenation of light alkanes over metal-based heterogeneous catalysts DOI
Yingbin Zheng, Xinbao Zhang, Junjie Li

et al.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2024, Volume and Issue: 65, P. 40 - 69

Published: Oct. 1, 2024

Language: Английский

Citations

3
Promoting n-Butane Dehydrogenation over PtMn/SiO2 through Structural Evolution Induced by a Reverse Water-Gas Shift Reaction DOI
Yi Liu, Guanghui Zhang, Shida Liu

et al.

ACS Catalysis, Journal Year: 2022, Volume and Issue: 12(21), P. 13506 - 13512

Published: Oct. 20, 2022

Structural evolution of heterogeneous catalysts often occurs during catalytic reactions. In this contribution, the structural a PtMn/SiO2 catalyst reverse water-gas shift (RWGS) reaction was investigated using detailed spectroscopic characterizations. The results show that Mn atoms on PtMn nanoparticle surface were partially removed RWGS reaction, which increases ratio Pt sites with lower coordination number surface, leading to 10-fold increase rate in n-C4H10 dehydrogenation from 1.85 21.93 mol gPt–1 h–1 and decrease apparent activation energy 50 33 kJ mol–1. This work provides dimension improving performance alkane over Pt-based bimetallic through CO2 hydrogenation.

Language: Английский

Citations

14