SusMat,
Journal Year:
2023,
Volume and Issue:
3(4), P. 442 - 470
Published: Aug. 1, 2023
Abstract
As
an
eco‐friendly
oxidant
and
energy
carrier,
H
2
O
is
used
in
various
fields.
The
industrial
production
of
mostly
depends
on
the
large‐scale
anthraquinone
oxidation
processes
with
high
costs.
Electrocatalytic
has
attracted
attention
as
a
renewable
cost‐effective
approach
to
replace
traditional
ones.
With
recent
development
oxygen
reduction
reaction
(ORR)
catalysts,
remarkable
progress
electrocatalysts
for
electrocatalytic
by
2e
−
ORR
been
reported.
This
review
summarizes
detailed
overview
mechanism
efficient
catalysts.
catalysts
were
divided
into
three
parts:
noble
metal‐based
catalyst,
non‐noble
non‐metal‐based
catalyst.
influences
catalytic
activity
selectivity
also
discussed.
Finally,
this
explores
prospects
synthesis
potential
research
directions
electrocatalysts.
It
aims
offer
guidance
designing
inspire
further
innovation
synthesis.
Small,
Journal Year:
2022,
Volume and Issue:
18(32)
Published: July 17, 2022
Abstract
Tailoring
the
morphology
and
crystal
structure
of
metallene
is
critical
to
improve
its
electrocatalytic
performance.
In
this
work,
hetero‐phase
RhB
(
h
‐RhB
metallene)
with
amorphous/crystalline
readily
prepared
by
a
two‐step
method.
The
very
unique
in
non‐metallic
heteroatom
doping
structure.
Benefiting
from
optimized
electronic
states
induced
incorporation
B
atoms,
exhibits
superior
performance
for
hydrogen
evolution
reaction
peroxide
electro‐oxidation
(HPOR).
When
coupled
HPOR,
metallene||
water
electrolysis
two‐electrode
system
lower
cell
voltage
0.379
V
(@
10
mA
cm
−2
)
compared
overall
splitting
(1.35
V).
presented
synthetic
method
provides
powerful
strategy
design
energy‐saving
H
2
production.
Small Structures,
Journal Year:
2023,
Volume and Issue:
4(7)
Published: Jan. 4, 2023
Electrocatalytic
CO
2
reduction
reaction
(CO
RR)
to
produce
formate
(HCOOH)
attracts
special
interest
in
the
upgrade
of
waste
.
For
selective
conversion
into
HCOOH,
preferable
binding
*OCHO
compared
with
*COOH
is
a
prerequisite,
which
presents
great
challenge
rational
design
catalytic
active
center.
Recently,
alkaline‐earth
(AE)
metals
as
centers
have
been
reported
for
electrocatalysis.
Herein,
feasibility
AE
heterogeneous
catalysis
electrocatalytic
RR
toward
HCOOH
based
on
series
metal
single‐atom
catalysts
(SACs)
theoretically
studied.
High‐throughput
first‐principles
calculations
reveal
that,
all
studied
systems,
preferably
adsorb
*OCHO,
enabling
exclusive
production.
Especially,
Mg
SACs
embedded
graphene
and
Ca
SAC
anchored
g‐C
N
can
efficiently
convert
under
near‐zero
potential,
both
systems
exhibit
high
stability.
Mechanistic
investigation
indicates
that
are
highly
ionic,
strongly
bind
mainly
through
electrostatic
attraction
interaction.
This
study
lays
theoretical
foundation
efficient
electroreduction
selectivity,
further
emphasizes
potential
catalysis.
Deleted Journal,
Journal Year:
2023,
Volume and Issue:
2, P. e9120078 - e9120078
Published: May 24, 2023
With
the
rapid
development
of
economy,
increasing
energy
crisis
and
environmental
pollution
urge
us
to
develop
sustainable
clean
novel
systems.
Among
them,
electrochemical
conversion
technology
is
considered
as
one
ideal
potential
alternative
systems,
electrocatalysts
play
critical
roles
but
are
still
challenging.
Metal-organic
frameworks
(MOFs),
thanks
their
regular
channels,
atomically
dispersed
active
centers,
adjustable
chemical
pore
environments,
have
severed
promising
for
conversion.
However,
relatively
low
conductivities
instabilities
MOFs
limit
wide
application
in
this
field.
In
case,
fabricating
hybrids
carbon-based
materials
an
effective
way
overcome
above
deficiencies.
addition,
synergistic
effects
between
carbons
could
optimize
electronic
structures
sites
promote
surface
areas,
thus
improve
electrocatalytic
performances
composites.
Herein,
we
outline
current
MOF/carbon
composites,
including
fabrication
methods
hybridized
with
various
dimensions
electrocatalysis
utilization
water
splitting,
hydrogen
evolution
reaction
(HER),
oxygen
(OER),
reduction
(ORR).
Finally,
advantages
challenges
such
catalysts
highlighted
future
endeavors
on
composites
HER,
OER
ORR
discussed.
SusMat,
Journal Year:
2023,
Volume and Issue:
3(4), P. 442 - 470
Published: Aug. 1, 2023
Abstract
As
an
eco‐friendly
oxidant
and
energy
carrier,
H
2
O
is
used
in
various
fields.
The
industrial
production
of
mostly
depends
on
the
large‐scale
anthraquinone
oxidation
processes
with
high
costs.
Electrocatalytic
has
attracted
attention
as
a
renewable
cost‐effective
approach
to
replace
traditional
ones.
With
recent
development
oxygen
reduction
reaction
(ORR)
catalysts,
remarkable
progress
electrocatalysts
for
electrocatalytic
by
2e
−
ORR
been
reported.
This
review
summarizes
detailed
overview
mechanism
efficient
catalysts.
catalysts
were
divided
into
three
parts:
noble
metal‐based
catalyst,
non‐noble
non‐metal‐based
catalyst.
influences
catalytic
activity
selectivity
also
discussed.
Finally,
this
explores
prospects
synthesis
potential
research
directions
electrocatalysts.
It
aims
offer
guidance
designing
inspire
further
innovation
synthesis.
