Direct acylation and alkynylation of hydrocarbons via synergistic decatungstate photo-HAT/nickel catalysis DOI
Wenfeng Liu, Yang Ke,

Chuhan Liu

et al.

Chemical Communications, Journal Year: 2022, Volume and Issue: 58(85), P. 11937 - 11940

Published: Jan. 1, 2022

Herein, we describe a protocol for the direct and selective acylation alkynylation of C(sp 3 )–H bonds saturated hydrocarbons by synergistic decatungstate photo-HAT nickel catalysis.

Language: Английский

Selective Functionalization of C(sp3)—H Bonds via Photoredox/ Nickel Dual Catalysis DOI
Xiaoqin Wang, Sheng Xu, Yuanyuan Ping

et al.

Chinese Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: 45(2), P. 383 - 383

Published: Jan. 1, 2025

Language: Английский

Citations

0
Dual Photoredox- and Titanium Catalysis-Enabled Three-Component Radical Propargylation of Aldehydes with 1,3-Enynes DOI

Xuehan Qi,

Renxu Cao,

Zhixian Wu

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 20, 2025

Herein, a straightforward and practical strategy involving radicals for the three-component carbonyl propargylation via dual photoredox titanium catalysis is presented. This delivers homopropargyl alcohols includes readily available starting materials, broad substrate scope, high functional group tolerance, mild reaction conditions. Catalytic Cp2TiCl2, recognized as an inexpensive, nontoxic, bench-stable source, employed.

Language: Английский

Citations

0
Trifluoromethyl Group (CF3) Induced Regioselective Larock Indole Synthesis from Unsymmetric β-CF3-1,3-enynes DOI

Yan‐Hua Qiu,

Peng-Xiang Ma,

Wen‐Hao Shao

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 24, 2025

The indole skeleton exists widely in natural products, pharmaceuticals, and materials. We disclose here a trifluoromethyl group induced regioselective Larock synthetic method from unsymmetric 2-CF3-1,3-enynes. presence of is determinable for the regioselectivity. Once CF3 was replaced with methyl or phenyl group, ratio 1:1 to 1:1.4 isomers were obtained. This strategy features good regioselectivity, broad substrate scope, high functional tolerance. protocol reported offers an alternative solution rare 3,4-functionalization products further transformed show distinctive reactivity hydroboration–oxidation hydro-bromination.

Language: Английский

Citations

0
Nickel-catalyzed carbonylative four-component 1,4-dicarbofunctionalization of 1,3-enynes DOI

Zhao Yan,

Qi-Chao Shan,

Xin Hong

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: 67(6), P. 2029 - 2038

Published: April 24, 2024

Language: Английский

Citations

3
Direct acylation and alkynylation of hydrocarbons via synergistic decatungstate photo-HAT/nickel catalysis DOI
Wenfeng Liu, Yang Ke,

Chuhan Liu

et al.

Chemical Communications, Journal Year: 2022, Volume and Issue: 58(85), P. 11937 - 11940

Published: Jan. 1, 2022

Herein, we describe a protocol for the direct and selective acylation alkynylation of C(sp 3 )–H bonds saturated hydrocarbons by synergistic decatungstate photo-HAT nickel catalysis.

Language: Английский

Citations

16