Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
62(25)
Published: April 18, 2023
The
development
of
aryl
alkyl
sulfides
as
dichotomous
electrophiles
for
site-selective
silylation
via
C-S
bond
cleavage
has
been
achieved.
Iron-catalyzed
selective
C(aryl)-S
bonds
can
occur
in
the
presence
β-diketimine
ligands,
and
C(alkyl)-S
be
achieved
by
t-BuONa
without
use
transition
metals,
resulting
corresponding
silylated
products
moderate
to
excellent
yields.
Mechanistic
studies
suggest
that
Fe-Si
species
may
undergo
metathesis
reactions
during
bonds,
while
silyl
radicals
are
involved
bonds.
Science Advances,
Journal Year:
2024,
Volume and Issue:
10(30)
Published: July 24, 2024
The
transformation
of
organoboron
compounds
plays
an
important
role
in
synthetic
chemistry,
and
recent
advancements
boron-migration
reactions
have
garnered
considerable
attention.
Here,
we
report
unprecedented
1,2-boron
migrative
acylation
upon
photocatalysis-facilitated
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(49)
Published: Aug. 13, 2024
Abstract
The
1,2‐hydroxysilylation
of
alkenes
is
crucial
for
synthesizing
organosilicon
compounds
which
are
key
intermediates
in
material
science,
pharmaceuticals,
and
organic
synthesis.
development
strategies
employing
hydrogen
atom
transfer
pathways
currently
hindered
by
the
existence
various
competing
reactions.
Herein,
we
reported
a
novel
mechanochemical
strategy
triphasic
through
single‐electron‐transfer
pathway.
Our
approach
not
only
circumvents
competitive
reactions
to
enable
first‐ever
unactivated
but
also
pioneers
research
mechanic
force‐induced
under
ambient
conditions.
This
gentle
method
offers
excellent
compatibility
with
functional
groups,
operates
simple
solvent‐free
conditions,
ensures
rapid
reaction
time.
Preliminary
mechanistic
investigations
suggest
that
silylboronate
can
be
transformed
silicon
radical
highly
polarized
Li
2
TiO
3
particles
oxygen
ball‐milling
condition.
Green Chemistry,
Journal Year:
2022,
Volume and Issue:
25(1), P. 256 - 263
Published: Dec. 8, 2022
A
visible
light-induced
organophotocatalytic
silyl
transfer
strategy
of
silylboranes
for
the
construction
C–Si
bonds
has
been
demonstrated,
where
methanol
association
with
boron
atoms
enables
photocatalytic
generation
radicals.
Chemical Science,
Journal Year:
2023,
Volume and Issue:
14(7), P. 1871 - 1877
Published: Jan. 1, 2023
Herein,
we
realized
the
quick
generation
of
stable
photoinduced
radicals
in
donor–acceptor
triarylphosphines
with
associated
color
changes
emission
and
absorption,
which
was
deciphered
by
electron
paramagnetic
resonance
(EPR)
spectra.
Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
62(25)
Published: April 18, 2023
The
development
of
aryl
alkyl
sulfides
as
dichotomous
electrophiles
for
site-selective
silylation
via
C-S
bond
cleavage
has
been
achieved.
Iron-catalyzed
selective
C(aryl)-S
bonds
can
occur
in
the
presence
β-diketimine
ligands,
and
C(alkyl)-S
be
achieved
by
t-BuONa
without
use
transition
metals,
resulting
corresponding
silylated
products
moderate
to
excellent
yields.
Mechanistic
studies
suggest
that
Fe-Si
species
may
undergo
metathesis
reactions
during
bonds,
while
silyl
radicals
are
involved
bonds.
