Bimetallic (or Multimetallic) Synthesis of N-Heterocycles

Catalysts, Journal Year: 2023, Volume and Issue: 13(9), P. 1268 - 1268

Published: Sept. 2, 2023

Bimetallic (or multimetallic) catalysis has emerged as a powerful tool in modern chemical synthesis, offering improved reaction control and versatility. This review focuses on the recent developments bimetallic sequential for synthesis of nitrogen heterocycles, which are essential building blocks pharmaceuticals fine chemicals. The cooperative action two (sometimes more) different metal catalysts enables intricate over pathways, enhancing selectivity efficiency N-heterocyclic compounds. By activating less reactive substrates, this multimetal catalytic strategy opens new synthetic possibilities challenging use materials systems reduces waste improves atom efficiency, aligning with green chemistry principles. With diverse range combinations conditions, provides access to broad array compounds various functionalities. paper highlights significant progress made past decade topic, emphasizing promising potential drug discovery industries.

Language: Английский

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Bimetallic (or Multimetallic) Synthesis of N-Heterocycles

Published: Aug. 4, 2023

Bimetallic (or multimetallic) catalysis has emerged as a powerful tool in modern chemical synthesis, offering improved reaction control and versatility. This review focuses on the recent de-velopments bimetallic sequential for synthesis of nitrogen heterocycles, essential building blocks pharmaceuticals fine chemicals. The cooperative action two (and sometimes more) different metal catalysts enables intricate over pathways, enhancing selectivity efficiency N-heterocyclic compounds synthesis. By activating less reactive substrates, this multimetal catalytic strategy opens new synthetic possibilities challenging compounds. use materials systems reduces waste improves atom efficiency, aligning with green chemistry principles. With diverse range combinations conditions, provides access to broad array various functionalities. paper highlights significant progress made past decade topic, emphasizing promising potential drug discovery industries.

Language: Английский

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Ir/Brønsted acid dual-catalyzed asymmetric synthesis of bisbenzannulated spiroketals and spiroaminals from isochroman ketals

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(20), P. 5831 - 5840

Published: Jan. 1, 2024

An Ir/Brønsted acid dual-catalyzed asymmetric cascade reaction of 2-(1-hydroxyallyl)phenols with isochroman ketals was developed, affording antifungal spiroketals high enantioselectivities.

Language: Английский

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Formation of Four-Membered Heterocycles

Elsevier eBooks, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Language: Английский

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Four-membered ring systems

Progress in heterocyclic chemistry, Journal Year: 2024, Volume and Issue: unknown, P. 59 - 87

Published: Jan. 1, 2024

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