Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 477, P. 146908 - 146908
Published: Oct. 24, 2023
Language: Английский
Chemical Society Reviews, Journal Year: 2023, Volume and Issue: 52(21), P. 7602 - 7664
Published: Jan. 1, 2023
Carbon nitrides, with feasibility of tailored band gap via suitable nanoarchitectonics, are deemed as best catalysts amongst existing materials, especially for HER, OWS, COR, NRR, water oxidation, pollutant removal, and organocatalysis.
Language: Английский
Citations
91
CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2023, Volume and Issue: 52, P. 127 - 143
Published: Sept. 1, 2023
Language: Английский
Citations
86
Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 16(1)
Published: Jan. 4, 2024
Over the past decade, graphitic carbon nitride (g-C
Language: Английский
Citations
69
Progress in Materials Science, Journal Year: 2024, Volume and Issue: 142, P. 101242 - 101242
Published: Jan. 21, 2024
Drawing inspiration from the natural process of photosynthesis found in plant leaves, scientists are exploring use photocatalysis to convert carbon dioxide (CO2) into valuable products using solar light and water. Photocatalytic CO2 conversion has emerged as one efficient green approaches revitalize environment greenhouse gas pollution. Owing its visible-range band gap, non-toxicity, ease synthesis at economic costs stability under irradiation, g-C3N4 most explored photocatalyst. However, due rampant exciton recombination owing poor electrical conductivity, efficiency reduction falls short for pure/pristine form. Therefore, structural manoeuvre materials N-rich configurations, heteroatom/single-atom doping hybridization with various functional including metal oxides/sulfides, perovskite halides complexes been adopted, thereby overcoming their inherent drawbacks photocatalytic reduction. In this timely review, we present an overview recent advances surface/interface engineering nitrides fuels useful chemical by-products. More importance is given critical evaluation surface manipulation how it amplifies affects properties Finally, provide a comprehensive outlook future directions these functionalised applications. We strongly believe that unique review will offer new knowledge on property relationship nitride-based impact enhancing performance reactions further create opportunities them areas.
Language: Английский
Citations
66
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 485, P. 149855 - 149855
Published: Feb. 21, 2024
Language: Английский
Citations
48
EES Catalysis, Journal Year: 2024, Volume and Issue: 2(2), P. 411 - 447
Published: Jan. 1, 2024
This review comprehensively summarizes the recent advances on crystalline carbon nitrides, including their preparation, optimization strategies, photocatalytic applications, as well challenges and prospects.
Language: Английский
Citations
39
Proceedings of the National Academy of Sciences, Journal Year: 2024, Volume and Issue: 121(4)
Published: Jan. 17, 2024
Nonradicals are effective in selectively degrading electron-rich organic contaminants, which unfortunately suffer from unsatisfactory yield and uncontrollable composition due to the competitive generation of radicals. Herein, we precisely construct a local microenvironment carbon nitride–supported high-loading (~9 wt.%) Fe single-atom catalyst (Fe SAC) with sulfur via facile supermolecular self-assembly strategy. Short-distance S coordination boosts peroxymonosulfate (PMS) activation generates high-valent iron–oxo species IV =O) along singlet oxygen ( 1 O 2 ), significantly increasing yield, PMS utilization, p -chlorophenol reactivity by 6.0, 3.0, 8.4 times, respectively. The nonradicals is controllable simply changing content. In contrast, long-distance both radicals nonradicals, could not promote reactivity. Experimental theoretical analyses suggest that short-distance upshifts d -band center atom, i.e., being close Fermi level, changes binding mode between atom site generate =O high yield. S-coordinated SAC exhibits excellent application potential various water matrices. These findings can guide rational design robust SACs toward selective utilization.
Language: Английский
Citations
36
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 482, P. 148844 - 148844
Published: Jan. 21, 2024
Language: Английский
Citations
32
Science China Materials, Journal Year: 2024, Volume and Issue: 67(2), P. 397 - 423
Published: Jan. 5, 2024
Language: Английский
Citations
20
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(45)
Published: May 31, 2024
Abstract Photothermal elastomers are recognized as smart flexible materials that can rapidly and effectively convert light energy into heat energy. However, there has been a lack of adequate focus on tackling the sustainability challenges photothermal elastomers, particularly in terms material selection, integration complex functionalities, final disposal. A fully bio‐derived elastomer (BPTE) produced through simple chemical‐free approach is introduced, utilizing alkali lignin, lipoic acid, phytic acid feedstocks. The BPTE exhibits an adaptive polymeric network crosslinked by dynamic covalent disulfide bonds multiple hydrogen bonds, endowing it with dual‐mode conversion capability, robustness, stretchability, self‐healing property, hydrophobicity, swelling resistance, self‐adhesion, full recyclability, degradability. further demonstrated next‐generation solution for generators, light‐driven actuators, antibacterial dressings, fibers. versatility opens avenues innovative devices systems significant potential conversion, soft robotics, medical treatment, clothing. With outstanding performances, biodegradability, these bio‐based present attractive prospect development advanced products.
Language: Английский
Citations
20