Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142353 - 142353
Published: April 1, 2025
Language: Английский
Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142353 - 142353
Published: April 1, 2025
Language: Английский
Inorganic Chemistry, Journal Year: 2025, Volume and Issue: 64(10), P. 4784 - 4790
Published: March 5, 2025
A novel magnetic hollowed CoFe@C-650 prism catalyst has been successfully prepared and applied in the N-alkylation of alcohols amines through a hydrogen borrowing strategy. The demonstrates good to excellent activities reaction with broad substrate scope afford up 99% yield target products. preliminary mechanistic study reveals that high valent Co species may promote adsorption conversion alcohols, while Fe assists hydrogenating imine intermediates.
Language: Английский
Citations
0Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 535, P. 216610 - 216610
Published: March 21, 2025
Language: Английский
Citations
0Molecules, Journal Year: 2025, Volume and Issue: 30(7), P. 1639 - 1639
Published: April 7, 2025
The production of formic acid (FA) from lignocellulose and its derived sugars represents a pivotal upgrading reaction in biorefinery. This work prepared Mn-Mo doped carbon nanotube composite catalyst for the catalytic oxidation glucose into FA an O2 atmosphere, under extremely low Mn (3.27%) Mo (0.40%) loading conditions, displaying comparable performance with traditional vanadium-based suffering toxicity issues. It was confirmed that doping led to formation MnMoOX increased contents low-valence species (Mn2+ + Mn3+), lattice oxygen (Olatt), surface adsorbed (Oads) based on various characterization methods, such as XRD, XPS, TEM ICP, which were beneficial improve performance. maximum yield 58.8% could be achieved over Mn9Mo1OX@MWCNT after 6 h at 140 °C, far more than obtained undoped MnOX@MWCNT (14.5%) identical conditions. Glyoxylic arabinose identified two main intermediates, suggesting transformation involved different paths. proved manganese-based green alternative via oxidation.
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137547 - 137547
Published: April 1, 2025
Language: Английский
Citations
0Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142353 - 142353
Published: April 1, 2025
Language: Английский
Citations
0