ZrO2 promoted Ru/In2O3 catalyst for selective hydrogenation of CO2 to methanol DOI
Shilong Xiong, Zhe Lü, Chenyang Shen

et al.

Chemical Engineering Science, Journal Year: 2023, Volume and Issue: 282, P. 119246 - 119246

Published: Sept. 3, 2023

Language: Английский

CO2 hydrogenation to methanol over the copper promoted In2O3 catalyst DOI
Rui Zou, Chenyang Shen, Kaihang Sun

et al.

Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 93, P. 135 - 145

Published: Jan. 24, 2024

Language: Английский

Citations

36
Selectivity control in CO2 hydrogenation to one-carbon products DOI
Jingting Hu, Yafeng Cai,

Jinghao Xie

et al.

Chem, Journal Year: 2024, Volume and Issue: 10(4), P. 1084 - 1117

Published: March 13, 2024

Language: Английский

Citations

25
Nature of metal-support interaction for metal catalysts on oxide supports DOI
Tairan Wang,

Jianyu Hu,

Runhai Ouyang

et al.

Science, Journal Year: 2024, Volume and Issue: 386(6724), P. 915 - 920

Published: Nov. 21, 2024

The metal-support interaction is one of the most important pillars in heterogeneous catalysis, but developing a fundamental theory has been challenging because intricate interfaces. Based on experimental ‎data, interpretable machine learning, theoretical derivation, and first-principles simulations, we established ‎general metal-oxide interactions grounded ‎metal-metal metal-oxygen interactions. applies to metal nanoparticles atoms oxide supports films supports. We found that for late-transition catalysts, metal-metal dominated support effects suboxide encapsulation over nanoparticles. A principle strong occurrence formulated substantiated by extensive ‎experiments including 10 metals 16 ‎oxides. valuable insights revealed (strong) advance interfacial design supported catalysts.

Language: Английский

Citations

22
Deep Insight into Characterizing the Metal–Support Interface in Heterogeneous Catalysis DOI
Junhong Liu, Liwei Chen, Xi Liu

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(3), P. 1987 - 2002

Published: Jan. 23, 2024

Supported metal species are widely used as catalysts in heterogeneous catalysis. Apart from the extended surfaces, metal–support interfaces also play a crucial role catalytic performance due to their distinct electronic and geometric structures. However, complexity diversity of hinder further understanding nature active sites for reactions. Fortunately, recent advancements characterization techniques have uncovered deeper insights. This Perspective aims comprehensively summarize breakthroughs characterizing catalysts. summary facilitates interpretation these both macroscopic microscopic aspects, ultimately contributing fundamental structure–activity relationship.

Language: Английский

Citations

20
Nickel-modified In2O3 with inherent oxygen vacancies for CO2 hydrogenation to methanol DOI
Zixuan Zhou, Yuchen Wang,

Yuanjie Bao

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: 67(5), P. 1715 - 1728

Published: Jan. 23, 2024

Language: Английский

Citations

17
Thermochemical CO2 Reduction to Methanol over Metal-Based Single-Atom Catalysts (SACs): Outlook and Challenges for Developments DOI

Huibo Zhao,

Xiaochen Liu,

Chunyang Zeng

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(34), P. 23649 - 23662

Published: Aug. 20, 2024

The conversion of thermodynamically inert CO

Language: Английский

Citations

17
Atomically Dispersed Cu on In2O3 for Relay Electrocatalytic Conversion of Nitrate and CO2 to Urea DOI
Ying Zhang, Zhuohang Li,

Chaofan Qiang

et al.

ACS Nano, Journal Year: 2024, Volume and Issue: 18(36), P. 25316 - 25324

Published: Aug. 26, 2024

Urea electrosynthesis from coelectrolysis of NO

Language: Английский

Citations

16
Design of catalysts for selective CO2 hydrogenation DOI
Runping Ye, Jie Ding, Tomás Ramı́rez Reina

et al.

Nature Synthesis, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 27, 2025

Language: Английский

Citations

2
Enhanced Surface Charge Localization Over Nitrogen-Doped In2O3 for CO2 Hydrogenation to Methanol with Improved Stability DOI
Yuxiang Yang, Chenyang Shen, Kaihang Sun

et al.

ACS Catalysis, Journal Year: 2023, Volume and Issue: 13(9), P. 6154 - 6168

Published: April 20, 2023

Indium oxide (In2O3) is active and promising for selective hydrogenation of CO2 to methanol. However, it suffers from over-reduction at elevated temperatures, causing deactivation. Herein, a nitrogen-doped In2O3 (N–In2O3) catalyst was prepared using plasma-intensified nitrogen-doping technology. It confirmed that nitrogen doping effective the stabilization In2O3. The doped enhances surface charge localization, which inhibits on limits generation excessive oxygen vacancies. also serves as site, synergistically with vacancy, leads an enhanced dissociation adsorbed CO* intermediates. electron-rich causes strong adsorption CO N–In2O3 formation free CO. A significantly improved methanol selectivity higher turnover frequency (TOF) thus achieved N–In2O3, compared un-doped For example, 21,000 cm3 h–1 gcat–1, 300 °C, 5 MPa, TOF reaches 37.0 75.1%, while only 16.0 62.3%. Different pristine In2O3, takes route This explains reason why possesses

Language: Английский

Citations

39
Confining ultrafine Pt nanoparticles on In2O3 nanotubes for enhanced selective methanol production by CO2 hydrogenation DOI
Yuhan Wang, Yue Liu, Li Tan

et al.

Journal of Materials Chemistry A, Journal Year: 2023, Volume and Issue: 11(48), P. 26804 - 26811

Published: Jan. 1, 2023

The Pt@In 2 O 3 catalyst attains the homogeneous dispersion of Pt particles on In substrate with strong contact via a confinement effect for enhanced methanol production from CO hydrogenation.

Language: Английский

Citations

38