Photoredox/Nickel Dual-Catalysis-Enabled Regioselective Cyclization of Alkenes with Alkyl Chlorides DOI

Xuege Yang,

Lou Shi, Ruoyu Qin

et al.

Published: Jan. 1, 2023

A photoredox/nickel dual catalysis is presented for the construction of several kinds useful nitrogen-containing heterocycles. This protocol regioselective and features a broad substrate scope. It provides direct access to heterocycles by reacting alkyl chlorides with readily available activated unactivated alkenes. Moreover, this can be easily scalable gram-scale, it feasible use sunlight as light source. Mechanistic studies suggest that energy transfer pathway involved in catalytic process.

Language: Английский

Photoredox/Nickel Dual-Catalysis-Enabled Regioselective Cyclization of Alkenes with Alkyl Chlorides DOI

Xuege Yang,

Lou Shi, Ruoyu Qin

et al.

Published: Jan. 1, 2023

A photoredox/nickel dual catalysis is presented for the construction of several kinds useful nitrogen-containing heterocycles. This protocol regioselective and features a broad substrate scope. It provides direct access to heterocycles by reacting alkyl chlorides with readily available activated unactivated alkenes. Moreover, this can be easily scalable gram-scale, it feasible use sunlight as light source. Mechanistic studies suggest that energy transfer pathway involved in catalytic process.

Language: Английский

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